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torisob [31]
3 years ago
12

a solution of unknown molecular substance is prepared by dissolving 0.50g of the unknown in 8.0g of benzene. the solution freeze

s at 3.9. determine the molar mass of the unknown
Chemistry
1 answer:
spayn [35]3 years ago
6 0

Answer:

THE MOLAR MASS OF THE UNKNOWN MOLECULAR SUBSTANCE IS 200 G/MOL.

Explanation:

Mass of the unknown substance = 0.50 g

Freezing point of the solution = 3.9 °C

Freezing point of pure benzene = 5.5 °C

Freezing point dissociation constant Kf = 5.12°C/m

First, calculate the temperature difference between the freezing point of pure benzene and the final solution freezing point.

Change in temperature = 5.5 -3.9 = 1.6 °C

Next is to calculate the number of moles or molarity of the compound that dissolved.

Using the formula:

Δt = i Kf m

Assume i = 1

So,

1.6 °C = 1 * 5.12 * x/ 0.005 kg of benzene

x = 1.6 * 0.008 / 5.12

x = 0.0128 / 5.12

x = 0.0025 moles.

Next is to calculate the molar mass using the formula, molarity = mass / molar mass

Molar mass = mass / molarity

Molar mass = 0.50 g /0.0025

Molar mass = 200 g/mol

Hence, the molar mass of the unknown compound is 200 g/mol

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Calculate the concentration of formate in a 100mm solution of formic acid at ph 4.15. The pka for formic acid is 3.75
MissTica

The molarity of formic acid is 100 mM or 100\times 10^{-3}M. The dissociation reaction of formic acid is as follows:

HCOOH\leftrightharpoons HCOO^{-}+H^{+}

The expression for dissociation constant of the reaction will be:

K_{a}=\frac{[HCOO^{-}][H^{+}]}{[HCOOH]}

Rearranging,

[HCOO^{-}]=\frac{K_{a}[HCOOH]}{[H^{+}]}

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