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kotykmax [81]
3 years ago
9

Determine the equilibrium pH and speciation (concentration of each species) of the following two solutions. Neglect activity cor

rections. Species added Total concentration (solution a) HCl 10-3 M (solution b) NaCl 10-3 g.
Chemistry
1 answer:
irina [24]3 years ago
5 0

Answer:

HCl solution - H30+ and Cl ions. pH 3

NaCl - Na+ and Cl-. pH 7

Explanation:

a) HCl solution - the hydrogen ion combines with water molecule to form the hydronium molecule which is responsible for acidity. The chloride ion is also found in solution.

pH = -log [H+] = -log(10^-3) = 3

b) NaCl 10-3 g. The solid dissocates in water forming the Na+ and Cl- ions. None of these ions affect pH

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Water (H
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Water (H
2O)





NamesIUPAC name

water, oxidane

Other names

Hydrogen hydroxide (HH or HOH), hydrogen oxide, dihydrogen monoxide (DHMO) (systematic name[1]), hydrogen monoxide, dihydrogen oxide, hydric acid, hydrohydroxic acid, hydroxic acid, hydrol,[2] μ-oxido dihydrogen

Identifiers

CAS Number

7732-18-5 

3D model (JSmol)

Interactive image

Beilstein Reference

3587155ChEBI

CHEBI:15377 

ChEMBL

ChEMBL1098659 

ChemSpider

937 

Gmelin Reference

117

PubChem CID

962

RTECS numberZC0110000UNII

059QF0KO0R 

InChI

InChI=1S/H2O/h1H2 

Key: XLYOFNOQVPJJNP-UHFFFAOYSA-N 

SMILES

O

Properties

Chemical formula

H
2OMolar mass18.01528(33) g/molAppearanceWhite crystalline solid, almost colorless liquid with a hint of blue, colorless gas[3]OdorNoneDensityLiquid:[4]
0.9998396 g/mL at 0 °C
0.9970474 g/mL at 25 °C
0.961893 g/mL at 95 °C
Solid:[5]
0.9167 g/ml at 0 °CMelting point0.00 °C (32.00 °F; 273.15 K) [a]Boiling point99.98 °C (211.96 °F; 373.13 K) [6][a]SolubilityPoorly soluble in haloalkanes, aliphaticand aromatic hydrocarbons, ethers.[7]Improved solubility in carboxylates, alcohols, ketones, amines. Miscible with methanol, ethanol, propanol, isopropanol, acetone, glycerol, 1,4-dioxane, tetrahydrofuran, sulfolane, acetaldehyde, dimethylformamide, dimethoxyethane, dimethyl sulfoxide, acetonitrile. Partially miscible with Diethyl ether, Methyl Ethyl Ketone, Dichloromethane, Ethyl Acetate, Bromine.Vapor pressure3.1690 kilopascals or 0.031276 atm[8]Acidity (pKa)13.995[9][10][b]Basicity (pKb)13.995Conjugate acidHydroniumConjugate baseHydroxideThermal conductivity0.6065 W/(m·K)[13]

Refractive index (nD)

1.3330 (20 °C)[14]Viscosity0.890 cP[15]Structure

Crystal structure

Hexagonal

Point group

C2v

Molecular shape

Bent

Dipole moment

1.8546 D[16]Thermochemistry

Heat capacity (C)

75.375 ± 0.05 J/(mol·K)[17]

Std molar
entropy (So298)

69.95 ± 0.03 J/(mol·K)[17]

Std enthalpy of
formation (ΔfHo298)

−285.83 ± 0.04 kJ/mol[7][17]

Gibbs free energy (ΔfG˚)

−237.24 kJ/mol[7]
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