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3 years ago

Los isomeros ópticos

Chemistry

1 answer:

krek1111 [17]3 years ago

7 0

Answer:

Los isómeros ópticos son dos compuestos que contienen el mismo número y tipo de átomos, y enlaces (es decir, la conectividad entre los átomos es la misma), y diferentes disposiciones espaciales de los átomos, pero que tienen imágenes especulares no superponibles. Cada estructura de imagen especular no superponible se denomina enantiómero.

Explanation

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(b) The temperature of the vapor in the flask in Kelvin is, 372.7 K

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Explanation : Given,

Mass of empty flask and stopper = 55.844 g

Volume of liquid = 5 mL

Temperature = $99.7^oC$

Mass of flask and condensed vapor = 56.101 g

Volume of flask = 248.1 mL

Barometric pressure in the laboratory = 752 mmHg

(a) First we have to determine the pressure of the vapor in the flask in atm.

Pressure of the vapor in the flask = Barometric pressure in the laboratory = 752 mmHg

Conversion used :

$1atm=760mmHg$

or,

$1mmHg=\frac{1}{760}atm$

As, $1mmHg=\frac{1}{760}atm$

So, $752mmHg=\frac{752mmHg}{1mmHg}\times \frac{1}{760}atm=0.989atm$

Thus, the pressure of the vapor in the flask in atm is, 0.989 atm

(b) Now we have to determine the temperature of the vapor in the flask in Kelvin.

Conversion used :

$K=273+^oC$

As, $K=273+^oC$

So, $K=273+99.7=372.7$

Thus, the temperature of the vapor in the flask in Kelvin is, 372.7 K

Now we have to determine the volume of the flask in liters.

Conversion used :

1 L = 1000 mL

or,

1 mL = 0.001 L

As, 1 mL = 0.001 L

So, 248.1 mL = 248.1 × 0.001 L = 0.2481 L

Thus, the volume of the flask in liters is, 0.2481 L

(c) Now we have to determine the mass of vapor that was present in the flask.

Mass of flask and condensed vapor = 56.101 g

Mass of empty flask and stopper = 55.844 g

Mass of vapor in flask = Mass of flask and condensed vapor - Mass of empty flask and stopper

Mass of vapor in flask = 56.101 g - 55.844 g

Mass of vapor in flask = 0.257 g

Thus, the mass of vapor present in the flask was, 0.257 g

(d) Now we have to determine the number of moles of vapor present.

Using ideal gas equation:

PV = nRT

where,

P = Pressure of vapor = 0.989 atm

V = Volume of vapor = 0.2481 L

n = number of moles of vapor = ?

R = Gas constant = 0.0821 L.atm/mol.K

T = Temperature of vapor = 372.7 K

Putting values in above equation, we get:

$(0.989atm)\times 0.2481L=n\times (0.0821L.atm/mol.K)\times 372.7K\\\\n=0.00802mole$

Thus, the number of moles of vapor present are 0.00802 mole.

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$\text{Mass of one mole of vapor}=\frac{\text{Mass of vapor}}{\text{Moles of vapor}}$

$\text{Mass of one mole of vapor}=\frac{0.257g}{0.00802mole}=32.0g/mole$

Thus, the mass of one mole of vapor is 32.0 g/mole

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