Answer:
This reactivity order reflects both the strength of the C–X bond, and the stability of X(–) as a leaving group, and leads to the general conclusion that alkyl iodides are the most reactive members of this functional class.
We are given the base dissociation constant, Kb, for Pyridine (C5H5N) which is 1.4x10^-9. The acid dissociation constant, Ka for the Pyridium ion or the conjugate acid of Pyridine is to be determined. We know from our chemistry classes that:
Kw = Kb * Ka
where Kw is always equal to 1x10^-14
so, to solve for Ka of Pyridium ion, substitute Kb to the equation together with Kw and solve for Ka:
1x10^-14 = 1.4x10^-9 * Ka
solve for Ka
Ka = 7.14x10^-6
Therefore, the acid dissociation constant of Pyridinium ion is 7.14x10^-6.
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