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Ulleksa [173]
3 years ago
10

Citric acid (C6H8O7) is a triprotic acid (It has 3 protons that can dissociate when dissolved) found naturally in lemon juice, a

nd it is widely used as a flavoring in beverages. What is the molarity of C6H8O7 in commercially available lemon juice if 14.26 mL of 1.751 M NaOH is required in a titration to neutralize 20.00 mL of the juice
Chemistry
1 answer:
Gnesinka [82]3 years ago
4 0

<u>Answer:</u> The molarity of citric acid that is commercially available lemon juice is 0.416 M

<u>Explanation:</u>

To calculate the concentration of acid, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is C_6H_8O_7

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=3\\M_1=?M\\V_1=20.00mL\\n_2=1\\M_2=1.751M\\V_2=14.26mL

Putting values in above equation, we get:

3\times M_1\times 20.00=1\times 1.751\times 14.26\\\\M_1=\frac{1\times 1.751\times 14.26}{3\times 20.00}=0.416M

Hence, the molarity of citric acid that is commercially available lemon juice is 0.416 M

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MnO₄⁻(aq) + I⁻(aq) → Mn²⁺(aq) + I₂(s)

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Oxidation: I⁻(aq) → I₂(s)

Step 2: Perform the mass balance, adding H⁺(aq) and H₂O(l) where appropriate

MnO₄⁻(aq) + 8 H⁺(aq) → Mn²⁺(aq) + 4 H₂O(l)

2 I⁻(aq) → I₂(s)

Step 3: Perform the charge balance, adding electrons where appropriate

MnO₄⁻(aq) + 8 H⁺(aq) + 5 e⁻ → Mn²⁺(aq) + 4 H₂O(l)

2 I⁻(aq) → I₂(s)  + 2 e⁻

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Step 5: Add both half-reactions and cancel what is repeated on both sides

2 MnO₄⁻(aq) + 16 H⁺(aq) + 10 e⁻ + 10 I⁻(aq) → 2 Mn²⁺(aq) + 8 H₂O(l) + 5 I₂(s)  + 10 e⁻

The balanced reaction is:

2 MnO₄⁻(aq) + 16 H⁺(aq) + 10 I⁻(aq) → 2 Mn²⁺(aq) + 8 H₂O(l) + 5 I₂(s)

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