In a combustion of a hydrocarbon compound, 2 reactions are happening per element:
C + O₂ → CO₂
2 H + 1/2 O₂ → H₂O
Thus, we can determine the amount of C and H from the masses of CO₂ and H₂O produced, respectively.
1.) Compute for the amount of C in the compound. The data you need to know are the following:
Molar mass of C = 12 g/mol
Molar mass of CO₂ = 44 g/mol
Solution:
0.5008 g CO₂*(1 mol CO₂/ 44 g)*(1 mol C/1 mol CO₂) = 0.01138 mol C
0.01138 mol C*(12 g/mol) = 0.13658 g C
Compute for the amount of H in the compound. The data you need to know are the following:
Molar mass of H = 1 g/mol
Molar mass of H₂O = 18 g/mol
Solution:
0.1282 g H₂O*(1 mol H₂O/ 18 g)*(2 mol H/1 mol H₂O) = 0.014244 mol H
0.014244 mol H*(1 g/mol) = 0.014244 g H
The percent composition of pure hydrocarbon would be:
Percent composition = (Mass of C + Mass of H)/(Mass of sample) * 100
Percent composition = (0.13658 g + 0.014244 g)/(<span>0.1510 g) * 100
</span>Percent composition = 99.88%
2. The empirical formula is determined by finding the ratio of the elements. From #1, the amounts of moles is:
Amount of C = 0.01138 mol
Amount of H = 0.014244 mol
Divide the least number between the two to each of their individual amounts:
C = 0.01138/0.01138 = 1
H = 0.014244/0.01138 = 1.25
The ratio should be a whole number. So, you multiple 4 to each of the ratios:
C = 1*4 = 4
H = 1.25*4 = 5
Thus, the empirical formula of the hydrocarbon is C₄H₅.
3. The molar mass of the empirical formula is
Molar mass = 4(12 g/mol) + 5(1 g/mol) = 53 g/mol
Divide this from the given molecular weight of 106 g/mol
106 g/mol / 53 g/mol = 2
Thus, you need to multiply 2 to the subscripts of the empirical formula.
Molecular Formula = C₈H₁₀
Answer:
The dissociation constant of phenol from given information is 
.
Explanation:
The measured pH of the solution = 5.153
Initially c
At eq'm c-x x x
The expression of dissociation constant is given as:
![K_a=\frac{[C_6H_5O^-][H^+]}{[C_6H_5OOH]}](https://tex.z-dn.net/?f=K_a%3D%5Cfrac%7B%5BC_6H_5O%5E-%5D%5BH%5E%2B%5D%7D%7B%5BC_6H_5OOH%5D%7D)
Concentration of phenoxide ions and hydrogen ions are equal to x.
![pH=-\log[x]](https://tex.z-dn.net/?f=pH%3D-%5Clog%5Bx%5D)
![5.153=-\log[x]](https://tex.z-dn.net/?f=5.153%3D-%5Clog%5Bx%5D)
The dissociation constant of phenol from given information is .
Answer:
That iron atom is oxidized. It loses two electrons.
Explanation:
Compare the formula of an iron atom and an iron(II) ion:
- Iron atom:
; - Iron(II) ion:
.
The superscript 
in the iron(II) ion is the only difference between the two formulas. This superscript indicates a charge of on each ion. Atoms and ions contain protons. In many cases, they also contain electrons. Each proton carries a positive charge of 
and each electron carries a charge of 
. Atoms are neutral for they contain an equal number of protons and electrons.
Protons are located at the center of atoms inside the nuclei. They cannot be gained or lost in chemical reactions. However, electrons are outside the nuclei and can be gained or lost. When an atom loses one or more electrons, it will carry more positive charge than negative charge. It will becomes a positive ion. Conversely, when an atom gains one or more electrons, it becomes a negative ion.
An iron atom will need to lose two electrons to become a positive iron(II) ion with a charge of on each ion. That is:
.
- Oxidation is Losing one or more electrons;
- Reduction is Gaining one or more electrons.
This definition can be written as the acronym OILRIG. (Khan Academy.)
In this case, each iron atom loses two electrons. Therefore the iron atoms here are oxidized.
Answer:
The molar mass and molecular weight of 3CaCl2 is 332.952.
