Question

At 14,000 ft elevation the air pressure drops to 0.59 atm. Assume you take a 1L sample of air at this altitude and compare it to 1 L of air taken at sea level. How much less O2 (in g) is available in 1 L of air at 14,000 ft (assume temperature of 298 K and that relative gas percentages are constant in both locations).

Answer 1

Answer:

There are 0.1125 g of O₂ less in 1 L of air at 14,000 ft than in 1 L of air at sea level.

Explanation:

To solve this problem we use the ideal gas law:

PV=nRT

Where P is pressure (in atm), V is volume (in L), n is the number of moles, T is temperature (in K), and R is a constant (0.082 atm·L·mol⁻¹·K⁻¹)

Now we calculate the number of moles of air in 1 L at sea level (this means with P=1atm):

1 atm * 1 L = n₁ * 0.082 atm·L·mol⁻¹·K⁻¹ * 298 K

n₁=0.04092 moles

Now we calculate n₂, the number of moles of air in L at an 14,000 ft elevation, this means with P = 0.59 atm:

0.59 atm * 1 L = n₂ * 0.082 atm·L·mol⁻¹·K⁻¹ * 298 K

n₂=0.02414 moles

In order to calculate the difference in O₂, we substract n₂ from n₁:

0.04092 mol - 0.02414 mol = 0.01678 mol

Keep in mind that these 0.01678 moles are of air, which means that we have to look up in literature the content of O₂ in air (20.95%), and then use the molecular weight to calculate the grams of O₂ in 20.95% of 0.01678 moles:

$0.01678mol*\frac{20.95}{100} *32\frac{g}{mol} =0.1125 gO_{2}$