Answer:
1) After adding 15.0 mL of the HCl solution, the mixture is before the equivalence point on the titration curve.
2) The pH of the solution after adding HCl is 12.6
Explanation:
10.0 mL of 0.25 M NaOH(aq) react with 15.0 mL of 0.10 M HCl(aq). Let's calculate the moles of each reactant.


There is an excess of NaOH so the mixture is before the equivalence point. When HCl completely reacts, we can calculate the moles in excess of NaOH.
NaOH + HCl ⇒ NaCl + H₂O
Initial 2.5 × 10⁻³ 1.5 × 10⁻³ 0 0
Reaction -1.5 × 10⁻³ -1.5 × 10⁻³ 1.5 × 10⁻³ 1.5 × 10⁻³
Final 1.0 × 10⁻³ 0 1.5 × 10⁻³ 1.5 × 10⁻³
The concentration of NaOH is:
![[NaOH]=\frac{1.0 \times 10^{-3} mol }{25.0 \times 10^{-3} L} =0.040M](https://tex.z-dn.net/?f=%5BNaOH%5D%3D%5Cfrac%7B1.0%20%5Ctimes%2010%5E%7B-3%7D%20mol%20%7D%7B25.0%20%5Ctimes%2010%5E%7B-3%7D%20L%7D%20%3D0.040M)
NaOH is a strong base so [OH⁻] = [NaOH].
Finally, we can calculate pOH and pH.
pOH = -log [OH⁻] = -log 0.040 = 1.4
pH = 14 - pOH = 14 - 1.4 = 12.6
In evaporation due to internal heat, kinetic energy of molecules increases and they come to the top and take out that heat with them when they evaporate thus causes cooling
in boiling as heat is given to the molecules so their kinetic energy increases and they start vibrating with great energy and thus causes heating
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