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Ganezh [65]
3 years ago
14

A solution was made by adding water to 0.250 g of H2Z until the volume totaled 25.00 mL. Subsequent titration required 40.50 mL

of 0.100 M sodium hydroxide. Calculate the molar mass of H2Z (in g/mol).
given: H2Z(aq) + 2 NaOH(aq) → Na 2Z(aq) + 2 H2O(ℓ)
Chemistry
1 answer:
Brilliant_brown [7]3 years ago
7 0

Answer:

123 g/mol

Explanation:

Let's consider the neutralization reaction.

H₂Z(aq) + 2 NaOH(aq) → Na₂Z(aq) + 2 H₂O(ℓ)

The moles of NaOH that reacted are:

40.50 \times 10^{-3} L \times \frac{0.100molNaOH}{1L} =4.05\times 10^{-3} molNaOH

The molar ratio of H₂Z to NaOH is 1:2. The moles of H₂Z that reacted are:

4.05\times 10^{-3} molNaOH \times \frac{1molH_{2}Z}{2molNaOH} =2.03\times 10^{-3} molH_{2}Z

The molar mass of H₂Z is:

\frac{0.250gH_{2}Z}{2.03\times 10^{-3} molH_{2}Z} =123g/mol

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Arrange the following aqueous solutions in order of decreasing freezing point: 0.10 m Na3PO4, 0.35 m NaCl, 0.20 m MgCl2, 0.15 m
GarryVolchara [31]

Answer: 0.35 m NaCl > 0.20 m MgCl_2 >0.10 m Na3PO_4 > 0.15 m CH_3COOH > 0.15 m C_6H_{12}O_6

Explanation:

Depression in freezing point:

T_f^0-T_f=i\times k_b\times m

where,

T_f= freezing point of solution

T^o_f = freezing point of solvent

k_f = freezing point constant

m = molality

1. For 0.10 m Na3PO_4

Na_3PO_4\rightarrow 3Na^++PO_4^{3-}

, i= 4 as it is a electrolyte and dissociate to give 4 ions. and concentration of ions will be 4\times 0.10=0.40

2. For 0.35 m NaCl

NaCl\rightarrow Na^++Cl^-

, i= 2 as it is a electrolyte and dissociate to give 2 ions. and concentration of ions will be 2\times 0.35=0.70 

3. For 0.20 m MgCl_2

MgCl_2\rightarrow Mg^{2+}+2Cl^-

, i= 3 as it is a electrolyte and dissociate to give 3 ions. and concentration of ions will be 3\times 0.20=0.60 

4. For 0.15 m C_6H_{12}O_6

, i= 1 as it is a non electrolyte and does not dissociate to give ions.

5. For 0.15 m CH_3COOH

CH_3COOH\rightarrow CH_3COO^-+H^+

, i= 2 as it is a electrolyte and dissociate to give 2 ions and thus have 2\times 0.15=0.30 

As concentration is highest for 0.35 m NaCl , freezing point depression will be highest and thus has lowest freezing point. As concentration is lowest for 0.15 m C_6H_{12}O_6 , freezing point depression will be lowest and thus has highest freezing point

8 0
3 years ago
a 25 ml sample of gas is in a syringe at 22C if it was cool down to 0 C what will the volume of the gas become
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Answer: 0.023 liters

Explanation:

Given that,

Original volume of gas (V1) = 25mL

[convert 25mL to liters

If 1000ml = 1L

25ml = 25/1000 = 0.025L]

Original temperature of gas (T1) = 22°C

[Convert 22°C to Kelvin by adding 273

22°C + 273 = 295K]

New volume of gas (V2) = ?

New temperature of gas (T2) = 0°C

[Convert 0°C to Kelvin by adding 273

0°C + 273 = 273K]

Since volume and temperature are given while pressure is held constant, apply the formula for Charle's law

V1/T1 = V2/T2

0.025L/295K = V2/273K

To get the value of V2, cross multiply

0.025L x 273K = 295K x V2

6.825L•K = 295K•V2

Divide both sides by 295K

6.825L•K/295K = 295K•V2/295K

0.023 L = V2

Thus, the new volume of the gas will be 0.023 litres

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