Let's divide the three experiments: The experiment with 10.00 mL of water is A), the experiment with 15.00 mL is B), and the experiment with 25.00 mL is C).
- (1) Now let's calculate the experimental density of each experiment. Density (ρ) is equal to the mass divided by the volume, thus:
- (2)To calculate the average density, we add each density and divide the result by the number of experiments (in this case 3):
- (3) The percent error is calculated by dividing the absolute value of the substraction of the theorethical and experimental values, by the theoretical value, times 100:
%error=
%error=
%error=2.44 %
69.9%
Explanation:
To find the mass percentage of iron in the compound in Fe₂O₃, we would go ahead to express the given molar mass of the iron to that of the compound.
Mass percentage = 
x 100
Molar mass of Fe = 55.85g/mol
Molar mass of O = 16g/mol
Molar mass of Fe₂O₃ = 2(55.85) + 3(16) = 159.7g/mol
Mass percentage = 
= 69.94% = 69.9%
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Constant Volume Calorimetry, also know as bomb calorimetry, is used to measure the heat of a reaction while holding volume constant and resisting large amounts of pressure. Although these two aspects of bomb calorimetry make for accurate results, they also contribute to the difficulty of bomb calorimetry. In this module, the basic assembly of a bomb calorimeter will be addressed, as well as how bomb calorimetry relates to the heat of reaction and heat capacity and the calculations involved in regards to these two topics.
Introduction
Calorimetry is used to measure quantities of heat, and can be used to determine the heat of a reaction through experiments. Usually a coffee-cup calorimeter is used since it is simpler than a bomb calorimeter, but to measure the heat evolved in a combustion reaction, constant volume or bomb calorimetry is ideal. A constant volume calorimeter is also more accurate than a coffee-cup calorimeter, but it is more difficult to use since it requires a well-built reaction container that is able to withstand large amounts of pressure changes that happen in many chemical reactions.
Most serious calorimetry carried out in research laboratories involves the determination of heats of combustion ΔHcombustion" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔHcombustionΔHcombustion, since these are essential to the determination of standard enthalpies of formation of the thousands of new compounds that are prepared and characterized each month. In a constant volume calorimeter, the system is sealed or isolated from its surroundings, and this accounts for why its volume is fixed and there is no volume-pressure work done. A bomb calorimeter structure consists of the following:
Steel bomb which contains the reactantsWater bath in which the bomb is submergedThermometerA motorized stirrerWire for ignition
is usually called a “bomb”, and the technique is known as bomb calorimetry
Another consequence of the constant-volume condition is that the heat released corresponds to qv , and thus to the internal energy change ΔUrather than to ΔH. The enthalpy change is calculated according to the formula
(1.1)ΔH=qv+ΔngRT" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: center; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; width: 10000em !important; position: relative;">ΔH=qv+ΔngRT(1.1)(1.1)ΔH=qv+ΔngRT
Δng" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔngΔng is the change in the number of moles of gases in the reaction.
Answer:
mass CaI2 = 23.424 Kg
Explanation:
From the periodic table we obtain for CaI2:
⇒ molecular mass CaI2: 40.078 + ((2)(126.90)) = 293.878 g/mol
∴ mol CaI2 = (4.80 E25 units )×(mol/6.022 E23 units) = 79.708 mol CaI2
⇒ mass CaI2 = (79.708 mol CaI2)×(293.878 g/mol) = 23424.43 g
⇒ mass CaI2 = 23.424 Kg
