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kifflom [539]
3 years ago
8

Using only the 1h nmr spectrum of the crude nitration product, determine if the product is mostly ortho-, meta-, or para- substi

tuted. (note: jortho= ~8 hz, jmeta= ~3 hz and jpara = ~1 hz. also aromatic protons ortho to no2 or c=o groups are generally downfield.)
a.major product(s) = _______________________________
b.describe how you came to your conclusi

Chemistry
1 answer:
tatiyna3 years ago
7 0
<span>The nitartion of methyl benzoate is expected to proceed as given in the equation below:

</span>

In methyl benzoate there are 3 types of 1 H proton. The two ortho to the C=O group is a doublet at 8 ppm the 2 metal to the C=O is a multiple at 7.5 ppm and one para to the C=O is a multiplet at 7.5 ppm.

On nitration the ortho will probably show two signal one being a single with 3 proton integration and one a doublet with 1 H integration

The meta will show a highly down field singlet (coresponding to 1 proton), two unequal doublets (corresponding to 1 H each) and one multiplets (corresponding to 1H). This is the major product as seen from the 1H NMR.

The para isomer will come as two doublets which will be very close to each other there is a small signal for this set between 8.2 and 8.3 ppm.

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149.3 g of H2O at 95 ◦C is poured over 412 g Fe at 5 ◦C in an insulated vessel. What is the final temperature? The specific heat
abruzzese [7]
You are correct, but you needn't worry about the signs so much. Just remember that the negative sign is used to denote a loss of energy; since the water is hotter, it will be losing energy (-Q) and the iron will gain energy (Q). Now, we substitute the values:
-149.3 * 4.184 * (T - 95) = 412 * 0.44 * (T - 5)
Solving this equation for T,
T = 74.8 °C
6 0
2 years ago
How many atoms are in 6.3 moles of lead
densk [106]

Answer:

3.79 x 10²⁴atoms

Explanation:

Given parameters:

Number moles of lead  = 6.3moles

Unknown:

Number of atoms  = ?

Solution:

To solve this problem,

              1 mole of a substance contains  6.02 x 10²³ atoms

            6.3 mole of Pb  will contain 6.3  x 6.02 x 10²³ = 3.79 x 10²⁴atoms

4 0
3 years ago
How many atoms are in 3 NaCl?
Assoli18 [71]

Explanation:

Sodium Chloride or NaCl is made up of two elements, sodium (or Na) and chlorine (or Cl). A molecule of sodium chloride, NaCl, consists of one atom each of sodium and chlorine. Hence, each molecule of NaCl has 2 atoms total.

5 0
2 years ago
Emily floats a note across a river to Dylan instead of directly passing it from her hand to Dylan's hand. If, in this scenario,
slega [8]

Answer: The Note

Explanation: Neurotransmitters are endogenous chemical substances that transmits signals through a NEUROMUSCULAR JUNCTIONS.

The signals are transmit from one NERVE CELL TO THE TARGET POINT such as Muscle cell,gland cell etc. Neurotransmissiom require the presence of synapse(the structure or medium through which neurosignals which can be an electrical or chemical signals to pass through).

8 0
3 years ago
Read 2 more answers
Use the solubility rules to determine if:
xenn [34]

<u>Answer:</u>

A reaction is said to occur if there is a formation of an insoluble solid or a precipitate(s) or a liquid (l) or a gas(g).

If both the reactants and products are in aqueous state, No reaction takes place.

$2 \mathrm{NaCl}(a q)+M g B r_{2}(a q)>M g C l_{2}(a q)+2 \mathrm{NaBr}(a q)(\mathrm{NO} \text { REACTION })$

All chlorides and Bromides are soluble except that of Ag, Hg and Pb.

Hence, No reaction takes place since all the reactants and products are in aqueous states.

${KOH}(a q)+{NaCl}(a q)>K C l(a q)+{NaOH}(a q)(\mathrm{NO} \text { REACTION })$

Salts  of Group IA are soluble. Hence No reaction takes place

$M g S(a q)+2 {NaOH}(a q)>M g(O H)_{2}(s)+N a_{2} S(a q)$

(REACTION TAKES PLACE)

All hydroxides are insoluble except that of Group IA, ammonium ion and  Group IIA down from Calcium.

Hence Reaction takes place with the formation of Mg(OH)_2 precipitate

5 0
3 years ago
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