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raketka [301]
3 years ago
11

A mixture of gaseous CO and H2, called synthesis gas, is used commercially to prepare methanol (CH3OH), a compound considered an

alternative fuel to gasoline. Under equilibrium conditions at 540.2 K, [H2] = 0.067 mol [CO]=0.021 mol/L and [CH3OH]=0.040 mol/L what is the value of Kc for this reaction at 505.0 K?
Chemistry
1 answer:
mr_godi [17]3 years ago
4 0

Answer : The value of equilibrium constant (K) is, 424.3

Explanation :  Given,

Concentration of H_2 at equilibrium = 0.067 mol

Concentration of CO at equilibrium = 0.021 mol

Concentration of CH_3OH at equilibrium = 0.040 mol

The given chemical reaction is:

CO+2H_2\rightarrow CH_3OH

The expression for equilibrium constant is:

K_c=\frac{[CH_3OH]}{[CO][H_2]^2}

Now put all the given values in this expression, we get:

K_c=\frac{(0.040)}{(0.021)\times (0.067)^2}

K_c=424.3

Thus, the value of equilibrium constant (K) is, 424.3

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Answer:

a) 62.1 kJ/mol

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d) -851.5 kJ/mol

Explanation:

The enthalpy change for a reaction in standard conditions (ΔH°rxn) can be calculated by:

ΔH°rxn = ∑n*ΔH°f, products - ∑n*ΔH°f, reagents

Where n is the number of moles in the stoichiometry reaction, and ΔH°f is the enthalpy of formation at standard conditions. ΔH°f = 0 for substances formed by only a single element. The values can be found in thermodynamics tables.

a) 2Ag₂O(s) → 4Ag(s) + O₂(g)

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ΔH°rxn = 0 - (2*(-31.05)) = 62.1 kJ/mol

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ΔH°f,CO(g) = -110.53 kJ/mol

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ΔH°rxn = [-393.51] - [-110.53 - 285.8] = 2.82 kJ/mol

c) Cr₂O₃(s) + 3H₂(g) → 2Cr(s) + 3H₂O(l)

ΔH°f,Cr₂O₃(s) = -1128.4 kJ/mol

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ΔH°rxn = [3*(-285.83)] - [( -1128.4)] = 270.91 kJ/mol

d) 2Al(s) + Fe₂O₃(s) → Al₂O₃(s) + 2Fe(s)

ΔH°f,Fe₂O₃(s) = -824.2 kJ/mol

ΔH°f,Al₂O₃(s) = -1675.7 kJ/mol

ΔH°rxn = [-1675.7] - [-824.2] = -851.5 kJ/mol

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