Answer: M = 22/ (i x28.948)
Explanation:
Pi = osmotic pressure = 22atm
T = Temperature = 353K
M = Molarity = ?
R = gas constant = 0.082atm.L/mol/K
i = van’t Hoff factor
Pi = iMRT
M= Pi /(iRT) = 22 / ( i x 0.082 x 353)
M = 22/ (i x28.948)
Using Charles's law; which states that the volume of an ideal gas is directly proportional to the absolute temperature at constant pressure.
That is; V α T
Hence; V1/T1 = V2/T2 = constant
V2 = V1 × (T2/T1)
= 250 × (350/300) = 291.67 mL
Therefore; the new volume will be 291.67 mL
Answer:
0.134 moles of H₂ can be formed if a 3.25g sample of Mg reacts with excess HCl
Explanation:
The balanced reaction is:
Mg + 2 HCl → MgCl₂ + H₂
By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles react:
- Mg: 1 mole
- HCl: 2 moles
- MgCl₂: 1 mole
- H₂: 1 mole
Being:
- Mg: 24. 31 g/mole
- H: 1 g/mole
- Cl: 35.45 g/mole
the molar mass of the compounds participating in the reaction is:
- Mg: 24.31 g/mole
- HCl: 1 g/mole + 35.45 g/mole= 36.45 g/mole
- MgCl₂: 24.31 g/mole + 2*35.45 g/mole= 95.21 g/mole
- H₂: 2*1 g/mole= 2 g/mole
Then, by stoichiometry of the reaction, the following quantities of mass participate in the reaction:
- Mg: 1 mole* 24.31 g/mole= 24.31 g
- HCl: 2 moles* 36.45 g/mole= 72.9 g
- MgCl₂: 1 mole* 95.21 g/mole= 95.21 g
- H₂: 1 mole* 2 g/mole= 2 g
Then you can apply the following rule of three: if by stoichiometry 24.31 grams of Mg form 1 mole of H₂, 3.25 grams of Mg how many moles of H₂ will they form?

moles of H₂= 0.134
<u><em>0.134 moles of H₂ can be formed if a 3.25g sample of Mg reacts with excess HCl</em></u>
Answer:
24.45 L
Explanation:
From General gas equation,
PV/T = P'V'/T'.................... Equation 1
Where P = initial pressure, V = Initial volume, T = Initial Temperature, P' = Final pressure, V' = Final Volume, T' = Final Temperature.
make V' the subject of the equation.
V' = PVT'/(TP')................. Equation 2
Given: P = 760 torr, V = 22.4 L, T = 0 °C = (0+273) = 273 K, T' = 25 °C = (25 + 273) = 298 K, P' = 760 torr
Substitute into equation 2
V' = 760(22.4)(298)/(760×273)
V' = 24.45 L.
Hence the volume of the gas = 24.45 L