Answer:
Following are the responses to the given question:
Explanation:
Since HN03 is an oxidation substance D-ribose u.ith oxidized to form in rubric acid Ribose is chiral, but rubric acid is achiral because of its symmetry mirror level, Hence no infrared roster in the sample holder is observed.
Please find the attached file.
D-Arabinose, on either hand, gives optical aldaric acid with such a net optical rotation observed inside the polarimeter for diagnosis with HN03.
Answer: The pressure will be 18.05 atm.
Explanation: Expression for ideal gas equation is :

where,
P = Pressure of the gas = ? atm
V = Volume of the gas = 0.333L
n = Number of moles of gas = 0.250 moles
R = Universal gas constant = 
T = temperature of the gas = 20°C = (273 + 20)K = 293K
Putting values in above equation, we get:

P = 18.05 atm
Answer:
Thus the order of covalent character will be
DG < EG < DF < DE
Explanation:
The electronegativity decides the nature of bond formed between two atoms.
More the difference in electronegativity more the ionic character in the bond formed.
Let us check the electronegativity difference between the elements forming molecules
a) DE :
3.8-3.3 = 0.5
b) DG :
3.8-1.3 = 2.5
c) EG
3.3-1.3 = 2
d) DF
3.8-2.8 = 1.3
So the maximum ionic character will be in DG and minimum in DE
Thus the order of covalent character will be
DG < EG < DF < DE
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