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3 years ago

How many moles of lithium are present in a sample that contains 2.45x10^87 formula units of Li2SO4?

Chemistry

1 answer:

ddd [48]3 years ago

3 0

The answer is: 8.14·10⁶³ moles of lithium are present.

N(Li₂SO₄) = 2.45·10⁸⁷; number of formula units of lithium sulfate.

n(Li₂SO₄) = N(Li₂SO₄) ÷ Na.

n(Li₂SO₄) = 2.45·10⁸⁷ ÷ 6.022·10²³ 1/mol.

n(Li₂SO₄) = 4.07·10⁶³ mol; amount of lithium sulfate

In one molecule of lithium sulfate, there are two atoms of lithium.

n(Li₂SO₄) : n(Li) = 1 : 2.

n(Li) = 2 · 4.07·10⁶³ mol.

n(Li) = 8.14·10⁶³ mol; amount of lithium atoms.

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3 years ago

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3 years ago

Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine.

zubka84 [21]

Answer: The value of $\Delta G^o$ of the reaction is 28.38 kJ/mol

Explanation:

For the given chemical reaction:

$SO_2(g)+Cl_2(g)\rightarrow SO_2Cl_2(g)$

The equation used to calculate enthalpy change is of a reaction is:

$\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]$

The equation for the enthalpy change of the above reaction is:

$\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(SO_2Cl_2(g))})]-[(1\times \Delta H^o_f_{(SO_2(g))})+(1\times \Delta H^o_f_{(Cl_2(g))})]$

We are given:

$\Delta H^o_f_{(SO_2Cl_2(g))}=-364kJ/mol\\\Delta H^o_f_{(SO_2(g))}=-296.8kJ/mol\\\Delta H^o_f_{(Cl_2(g))}=0kJ/mol$

Putting values in above equation, we get:

$\Delta H^o_{rxn}=[(1\times (-364))]-[(1\times (-296.8))+(1\times 0)]=-67.2kJ/mol=-67200J/mol$

The equation used to calculate entropy change is of a reaction is:

$\Delta S^o_{rxn}=\sum [n\times \Delta S^o_f_{(product)}]-\sum [n\times \Delta S^o_f_{(reactant)}]$

The equation for the entropy change of the above reaction is:

$\Delta S^o_{rxn}=[(1\times \Delta S^o_{(SO_2Cl_2(g))})]-[(1\times \Delta S^o_{(SO_2(g))})+(1\times \Delta S^o_{(Cl_2(g))})]$

We are given:

$\Delta S^o_{(SO_2Cl_2(g))}=311.9J/Kmol\\\Delta S^o_{(SO_2(g))}=248.2J/Kmol\\\Delta S^o_{(Cl_2(g))}=223.0J/Kmol$

Putting values in above equation, we get:

$\Delta S^o_{rxn}=[(1\times 311.9)]-[(1\times 248.2)+(1\times 223.0)]=-159.3J/Kmol$

To calculate the standard Gibbs's free energy of the reaction, we use the equation:

$\Delta G^o_{rxn}=\Delta H^o_{rxn}-T\Delta S^o_{rxn}$

where,

$\Delta H^o_{rxn}$ = standard enthalpy change of the reaction =-67200 J/mol

$\Delta S^o_{rxn}$ = standard entropy change of the reaction =-159.3 J/Kmol

Temperature of the reaction = 600 K

Putting values in above equation, we get:

$\Delta G^o_{rxn}=-67200-(600\times (-159.3))\\\\\Delta G^o_{rxn}=28380J/mol=28.38kJ/mol$

Hence, the value of $\Delta G^o$ of the reaction is 28.38 kJ/mol

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How many moles of lithium are present in a sample that contains 2.45x10^87 formula units of Li2SO4?​

How many moles of lithium are present in a sample that contains 2.45x10^87 formula units of Li2SO4?