Answer : The energy removed must be, 29.4 kJ
Explanation :
The process involved in this problem are :

The expression used will be:
![Q=[m\times c_{p,l}\times (T_{final}-T_{initial})]+[m\times \Delta H_{fusion}]+[m\times c_{p,s}\times (T_{final}-T_{initial})]](https://tex.z-dn.net/?f=Q%3D%5Bm%5Ctimes%20c_%7Bp%2Cl%7D%5Ctimes%20%28T_%7Bfinal%7D-T_%7Binitial%7D%29%5D%2B%5Bm%5Ctimes%20%5CDelta%20H_%7Bfusion%7D%5D%2B%5Bm%5Ctimes%20c_%7Bp%2Cs%7D%5Ctimes%20%28T_%7Bfinal%7D-T_%7Binitial%7D%29%5D)
where,
= heat released for the reaction = ?
m = mass of benzene = 94.4 g
= specific heat of solid benzene = 
= specific heat of liquid benzene = 
= enthalpy change for fusion = 
Now put all the given values in the above expression, we get:
![Q=[94.4g\times 1.73J/g.K\times (279-322)K]+[94.4g\times -125.6J/g]+[94.4g\times 1.51J/g.K\times (205-279)K]](https://tex.z-dn.net/?f=Q%3D%5B94.4g%5Ctimes%201.73J%2Fg.K%5Ctimes%20%28279-322%29K%5D%2B%5B94.4g%5Ctimes%20-125.6J%2Fg%5D%2B%5B94.4g%5Ctimes%201.51J%2Fg.K%5Ctimes%20%28205-279%29K%5D)

Negative sign indicates that the heat is removed from the system.
Therefore, the energy removed must be, 29.4 kJ
The empirical formula is the simplest form of the formula expressed in the lowest ratio. In this case, we just have to divide each subscript by the greatest common factor. Hence.
a. CN
b. P2O5
c.N2O5
d.NaCl
e. C9H20
f. BH3
g.K2Cr2O7
h.AlB3
i.CH
j.SiCl4
Answer and Explanation:
As the temperature of the substances increases, the average energy of the molecules increases, and average energy of attraction between the molecules decreases consequently intermolecular spacing between the molecules increases. As a result, a substance change in succession from gas to liquid to solid.
Given buffer:
potassium hydrogen tartrate/dipotassium tartrate (KHC4H4O6/K2C4H4O6 )
[KHC4H4O6] = 0.0451 M
[K2C4H4O6] = 0.028 M
Ka1 = 9.2 *10^-4
Ka2 = 4.31*10^-5
Based on Henderson-Hasselbalch equation;
pH = pKa + log [conjugate base]/[acid]
where pka = -logKa
In this case we will use the ka corresponding to the deprotonation of the second proton i.e. ka2
pH = -log Ka2 + log [K2C4H4O6]/[KHC4H4O6]
= -log (4.31*10^-5) + log [0.0451]/[0.028]
pH = 4.15