Answer : The balanced redox reaction will be,

Explanation :
The given chemical equation is,

In the half reaction method, the number of atoms in each half reaction and number of electrons must be balanced.
The half reactions in the acidic medium are :
Reduction :
......(1)
Oxidation :
.......(2)
Now multiply the equation (2) by 4 and then added both equation, we get the balanced redox reaction.
Thus, the balanced redox reaction will be,

Answer:
fraction of vacancies for this metal FV = 1.918*10⁻⁴
Explanation:
Given:
The number of vacancies per unit volume => ( Nv = 1*10²⁵ m⁻³ )
But we know that Avogrado's constant NA = 6.022*10²³ atoms/mol
Density of the material is given in g/cm3 we need to convert it to g/m³
Density of material ( p ) in g/m³ :
To convert we know that
1 g/cm³ = 1000000 g/m³ then
7.40 * ( 1000000 ) = 7.40*10⁶ g/m³
So, Density of material ( p ) in g/m³ = 7.40*10⁶ g/m³
Given Atomic mass = 85.5 g/mol
To Calculate the number of atomic sites per unit volume , we will use the below formula by substituting those values above
N = NA * p / A
N = ( 6.022*10²³ ) * ( 7.40*10⁶ ) / 85.5
N = 4.45*10³⁰ / 85.5
N = 5.212*10²⁸ atoms/m³
We can now Calculate the fraction of vacancies using the formula below;
Fv = Nv / N
Fv = 1*10²⁵ / 5.212*10²⁸
fraction of vacancies for this metal at 600c.= 1.918*10⁻⁴
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