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Svetlanka [38]
3 years ago
15

Part A What is the numerical value of Kc for the following reaction if the equilibrium mixture contains 0.51 M C3H6O, 0.30 M O2,

1.8 M CO2, and 2.0 M H2O? C3H6O(g)+4O2(g)⇌3CO2(g)+3H2O(g)
A) 2.4 × 101B) 1.1 × 104C) 8.9 × 10-5D) 4.3 × 10-2
Chemistry
1 answer:
bulgar [2K]3 years ago
3 0

Answer: 1.1\times 10^4

Explanation:

Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as K_c.

The given balanced equilibrium reaction is,

    C_3H_6O(g)+4O_2(g)\rightleftharpoons 3CO_2(g)+3H_2O(g)

 At eqm. conc.    (0.51) M   (0.30) M   (1.8) M    (2.0)M

The expression for equilibrium constant for this reaction will be,

K_c=\frac{[CO_2]^3\times [H_2O]^3}{[O_2]^4\times [C_3H_6O]^1}

Now put all the given values in this expression, we get :

K_c=\frac{(1.8)^3\times (2.0)^3}{(0.30)^4\times (0.51)^1}

K_c=1.1\times 10^4

Thus the value of the equilibrium constant is 1.1\times 10^4

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Answer:

1) 1.52 atm.

2) 647.85 K.

3) 20.56 L.

4) 1.513 mole.

5) 254.22 K = -18.77 °C.

Explanation:

  • In all this points, we should use the law of ideal gas to solve this problem: PV = nRT.
  • Where, P is the pressure (atm), V is the volume (L), n is the number of moles, R is the general gas constant (0.082 L.atm/mol.K), and T is the temperature (K).

1) In this point; n, R, and T are constants and the variables are P and V.

P and V are inversely proportional to each other that if we have two cases we get: P1V1 = P2V2.

<u><em>In our problem:</em></u>

P1 = ??? <em>(is needed to be calculated) </em>and V1 = 45.0 L.

P2 = 5.7 atm and V2 = 12.0 L.

Then, the original pressure (P1) = P2V2 / V1 = (5.7 atm x 12.0 L) / (45.0 L) = 1.52 atm.


2) In this case, n and R are the constants and the variables are P, V, and T.

P and V are inversely proportional to each other and both of them are directly proportional to the temperature of the gas that if we have two cases we get: P1V1T2 = P2V2T1.

<u><em>In our problem:</em></u>

P1 = 212.0 kPa, V1 = 32.0 L, and T1 = 20.0 °C = (20 °C + 273) = 293 K.

P2 = 300.0 kPa, V2= 50.0 L, and T2 = ??? <em>(is needed to be calculated) </em>

Then, the temperature in the second case (T2) = P2V2T1 / P1V1 = (300.0 kPa x 50.0 L x 293 K) / (212.0 kPa x 32.0 L) = 647.85 K.


3) In this case, P, n and R are the constants and the variables are V, and T.

V and T are directly proportional to each other that if we have two cases we get: V1T2 = V2T1.

<u><em>In our problem:</em></u>

V1 = 25.0 L and T1 = 65.0 °C + 273 = 338 K.

V2 = ??? <em>(is needed to be calculated) </em> and T2 = 5.0 °C + 273 = 278 K.

Herein, there is no necessary to convert T into K.

Then, the volume in the second case (V2) = V1T2 / T1 = (25.0 L x 278 °C) / (338 °C) = 20.56 L.


4) We can get the number of moles that will fill the container from: n = PV/RT.

P = 250.0 kPa, we must convert the unit from kPa to atm; <em><u>101.325 kPa = 1.0 atm</u></em>, then P = (1.0 atm x 250.0 kPa) / (101.325 kPa) = 2.467 atm.

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Now, n = PV/RT = (2.467 atm x 16.0 L) / (0.082 L.atm/mol.K x 318 K) = 1.513 mole.


5) In this case, V, n and R are the constants and the variables are P, and T.

P and T are directly proportional to each other that if we have two cases we get: P1T2 = P2T1.

<u><em>In our problem:</em></u>

P1 = 2200.0 mmHg and T1 = ??? <em>(is needed to be calculated) </em>.

P2 = 2700.0 mmHg and T2 = 39.0 °C + 273 = 312.0 K.

Herein, there is no necessary to convert P into atm.

Then, the temperature in the morning (T1) = P1T2 / P2 = (2200.0 mmHg x 312.0 K) / (2700.0 mmHg) = 254.22 K = -18.77 °C.

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