Explanation:
As per the Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
Hence, according to this law the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
..........(1)
..............(2)
The final reaction is as follows:
.............(3)
Therefore, adding (1) and (2) we get the final equation (3) and value of
at 298 K will be as follows.
=
+
= -314 kJ + (-80) kJ
= -394 kJ
Thus, we can conclude that
at 298 K for the given process is -394 kJ.
<span>Answer: 0.094%
</span><span>Explanation:
</span>
<span></span><span /><span>
1) Equilibrium chemical equation:
</span><span />
<span>Only the ionization of the formic acid is the important part.
</span><span />
<span>HCOOH(aq) ⇄ HCOO⁻(aq) + H⁺(aq).
</span><span />
<span>2) Mass balance:
</span><span />
<span> HCOOH(aq) HCOO⁻(aq) H⁺(aq).
Start 0.311 0.189
Reaction - x +x +x
Final 0.311 - x 0.189 + x x
3) Acid constant equation:
</span><span />
<span>Ka = [HCOO-] [N+] / [HCOOH] = (0.189 + x) x / (0.311 -x)
</span><span />
<span>= (0.189 + x )x / (0.311 - x) = 0.000177
4) Solve the equation:
You can solve it exactly (it will lead to a quadratic equation so you can use the quadratiic formula). I suggest to use the fact that x is much much smaller than 0.189 and 0.311.
</span><span />
<span>With that approximation the equation to solve becomes:
</span><span>0.1890x / 0.311 = 0.000177, which leads to:</span>
<span /><span>
x = 0.000177 x 0.311 / 0.189 = 2.91 x 10⁻⁴ M
5) With that number, the percent of ionization (alfa) is:
</span><span />
<span>percent of ionization = (moles ionized / initial moles) x 100 =
</span><span>
</span><span>
</span><span>percent ionization = (concentration of ions / initial concentration) x 100 =
</span><span>
</span><span>
</span><span>percent ionization = (0.000291 / 0.311)x 100 = 0.0936% = 0.094%
</span>
<span></span><span />
Answer:
In the reaction between p-aminophenol and acetic anhydride to form acetaminophen, 4.5 ml of water were added. This was done to recover the product out the container. Water was used as a means of carrying out the product out the container. However, it should be noted that we would want a small amount to be added in order to avoid the product dissolving onto it.
Explanation:
Answer:
Gases such as carbon dioxide diffuse much more slowly in water than in air. Plants that are fully submerged have greater difficulty obtaining the carbon dioxide they need. To help ameliorate this problem, underwater leaves lack a waxy coating because carbon dioxide is easier to absorb without this layer.
Explanation: