What is the pH of pure water at 40.0°C if the Kw at this temperature is 2.92 - 10-147 OA) 6.767 O B) 0 465 O c) 7.000 OD) 7 233
O E) 8.446
1 answer:
Answer:
PH= 6.767 (answer is the A option)
Explanation:
first we need to correct the value in Kw at this temperature is 2.92*10^-14
so, in this case we have that:
Kw=2.92*10^-14 M²
[ H3O^+] [ H3O^+]
![[H_{3}O^{+} ] [OH^{-} ] = Kw = 2.92*10^{-14} M^{2} \\\\](https://tex.z-dn.net/?f=%5BH_%7B3%7DO%5E%7B%2B%7D%20%20%5D%20%5BOH%5E%7B-%7D%20%20%5D%20%3D%20Kw%20%3D%202.92%2A10%5E%7B-14%7D%20M%5E%7B2%7D%20%20%20%5C%5C%5C%5C)
at 40ºC
![[H_{3}O^{+} ] = [OH^{-} ]](https://tex.z-dn.net/?f=%5BH_%7B3%7DO%5E%7B%2B%7D%20%20%5D%20%3D%20%5BOH%5E%7B-%7D%20%20%5D)
![[H_{3}O^{+} ]^{2} = 2.92*10^{-14} M^{2}](https://tex.z-dn.net/?f=%5BH_%7B3%7DO%5E%7B%2B%7D%20%20%5D%5E%7B2%7D%20%3D%202.92%2A10%5E%7B-14%7D%20M%5E%7B2%7D)
![[H_{3}O^{+} ] = (2.92*10^{-14})^{1/2} = 1.71*10^{-7} M](https://tex.z-dn.net/?f=%5BH_%7B3%7DO%5E%7B%2B%7D%20%20%5D%20%3D%20%282.92%2A10%5E%7B-14%7D%29%5E%7B1%2F2%7D%20%3D%201.71%2A10%5E%7B-7%7D%20M)
![PH= -log10[H_{3}O^{+} ] = -log10(1.71*10^{-7} ) = 6.767](https://tex.z-dn.net/?f=PH%3D%20-log10%5BH_%7B3%7DO%5E%7B%2B%7D%20%20%5D%20%3D%20-log10%281.71%2A10%5E%7B-7%7D%20%29%20%3D%206.767)
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