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hjlf
3 years ago
15

What is the pH of pure water at 40.0°C if the Kw at this temperature is 2.92 - 10-147 OA) 6.767 O B) 0 465 O c) 7.000 OD) 7 233

O E) 8.446
Chemistry
1 answer:
Sergeeva-Olga [200]3 years ago
7 0

Answer:

PH= 6.767     (answer is the A option)

Explanation:

first we need to correct the value in Kw at this temperature is 2.92*10^-14

so, in this case we have that:

Kw=2.92*10^-14 M²

[ H3O^+] [ H3O^+]

[H_{3}O^{+}  ] [OH^{-}  ] = Kw = 2.92*10^{-14} M^{2}   \\\\

at 40ºC

[H_{3}O^{+}  ] = [OH^{-}  ]

[H_{3}O^{+}  ]^{2} = 2.92*10^{-14} M^{2}

[H_{3}O^{+}  ] = (2.92*10^{-14})^{1/2} = 1.71*10^{-7} M

PH= -log10[H_{3}O^{+}  ] = -log10(1.71*10^{-7} ) = 6.767

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3 years ago
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Answer :

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Explanation :

According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.

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The intermediate balanced chemical reaction will be,

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(2) CO(g)+H_2O(g)\rightarrow CO_2(g)+H_2(g)    \Delta H_2=-41kJ

(3) CO(g)+3H_2(g)\rightarrow CH_4(g)+H_2O(g)    \Delta H_3=-206kJ

We are multiplying equation 1 by 2 and then adding all the equations, we get :

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\Delta H_{rxn}=2\times \Delta H_1+\Delta H_2+\Delta H_3

\Delta H_{rxn}=(2\times 29.7)+(-41)+(-206)

\Delta H_{rxn}=-187.6kJ/mol

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\Delta H=\frac{q}{n}

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q=\Delta H\times n

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q = heat = ?

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Now put all the given values in the above formula, we get:

q=(-187.6kJ/mol)\times (83.33mol)=-2.251kJ

Thus, the total heat will be, -2251 kJ

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