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MaRussiya [10]
4 years ago
15

Calculate Kc for the reaction: 2 HI(g) ⇄ H2(g) + I2(g) given that the concentrations of each species at equilibrium are as follo

ws: [HI] = 0.85 mol/L, [I2] = 0.60 mol/L, [H2] = 0.27 mol/L.
Chemistry
1 answer:
Paul [167]4 years ago
4 0

<u>Answer:</u> The value of K_c for the given reaction is 0.224

<u>Explanation:</u>

For the given chemical equation:

2HI(g)\rightleftharpoons H_2(g)+I_2(g)

The expression of K_c for given equation follows:

K_c=\frac{[H_2][I_2]}{[HI]^2}

We are given:

[HI]_{eq}=0.85M

[H_2]_{eq}=0.27M

[I_2]_{eq}=0.60M

Putting values in above expression, we get:

K_c=\frac{0.27\times 0.60}{(0.85)^2}=0.224

Hence, the value of K_c for the given reaction is 0.224

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tert-Butyl alcohol is a solvent with a Kf of 9.10 ∘C/m and a freezing point of 25.5 ∘C. When 0.807 g of an unknown colorless non
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Answer:

ethylene glycol (molar mass = 62.07 g/mol).

Explanation:

  • We can solve this problem using the relation:

<em>ΔTf = Kf.m,</em>

ΔTf is the depression in the freezing point of tert-Butyl alcohol (ΔTf = freezing point of pure solvent - freezing point in presence of unknown liquid = 25.5°C - 15.3°C = 10.2°C).

Kf is the molal freezing point constant of tert-Butyl alcohol (Kf = 9.1 °C/m).

m is the molality of unknown liquid.

∵ ΔTf = Kf.m

<em>∴ m = ΔTf/Kf </em>= (10.2°C)/(9.1 °C/m) = <em>1.121 m.</em>

  • We need to calculate the molar mass of the unknown liquid:

Molality (m) is the no. of moles of solute in 1.0 kg of solvent.

∴ m = (mass/molar mass) of unknown liquid/(mass of tert-Butyl alcohol (kg))

m = 1.121 m, mass of unknown liquid = 0.807 g, mass of tert-Butyl alcohol = 11.6 g = 0.0116 kg.

<em>∴ molar mass of unknown liquid = (mass of unknown liquid)/(m)(mass of tert-Butyl alcohol (kg)) </em>= (0.807 g)/(1.121 m)(0.0116 kg) = <em>62.06 g/mol.</em>

<em></em>

  • So, the unknown liquid is:

<em>ethylene glycol (molar mass = 62.07 g/mol).</em>

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