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Gwar [14]
3 years ago
11

Electron configurations based on Aufbau order of filling agree mostly with those derived experimentally, yet there are quite exc

eptions where errors in Aufbau configurations arise due to one (rarely two) misplaced electron. With the help of examples, discuss some of the limitations of Aufbau order.
Chemistry
1 answer:
marissa [1.9K]3 years ago
5 0

1) Aufbau principle is a scheme used to reproduce the electron configurations  of the ground states of atoms by successively filling subshells with electrons in a specific  order, filling subshells in the following order: 1s, 2s,  2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f.

First exceptions to the Aufbau principle is for example chromium atom (Cr).

Chromium has atomic number 24, it means it has 24 protons and 24 electrons.

The Aufbau principle predicts the configuration  [Ar] 3d⁴ 4s².

But the correct electron configuration of chromim atom is:

₂₄Cr 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s¹ or   [Ar] 3d⁵ 4s¹.

In chromium, half full d-sub level (3d) is more stable than a partially filled d sub-level (3d⁴), that is why an electron from the 4s orbital goes to a 3d orbital.

2) Second example is gallium atom (Ga).

Gallium has atomic number 31, it has 31 protons and 31 electrons.

The Aufbau principle predicts the configuration:

₃₁Ga 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p¹.

The correct electron configuration for gallium atom is:

₃₁Ga 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p¹.

That is because 3d subshell has lower energy, when is filled with electrons, than 4s subshell.

Valence electrons are in 4s and 4p orbitals, because when gallium loses three electrons, it has electron configuration:

₃₁Ga³⁺ 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰.

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valkas [14]

Answer:

Explanation:

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7 0
2 years ago
(01.01 MC)
lys-0071 [83]

The answer would be option B "I believe there is life on other planets." Scientific statements have a possibility to be wrong. It's not option A because option A is a opinion. It's not option C because option C is a fact. It's not option D because option D is a opinion.

Hope this helps!

8 0
3 years ago
Read 2 more answers
What are particles that differ in number between isotopes
balandron [24]

Answer:

Isotopes are atoms of the same element that have different numbers of neutrons but the same number of protons and electrons. The difference in the number of neutrons between the various isotopes of an element means that the various isotopes have different masses.

7 0
2 years ago
What’s the distance from the nucleus of an atom to its theoretical outer edge of electron orbits
ollegr [7]

Answer:

The range of atoms = (30-300 pm) depending upon the element

Explanation:

The Atomic radii of the atom is the distance from the center of the circle to the outermost orbital.

The center of the circle is the nucleus and the radii is the outermost boundary.

The actual size of the atom is decided on the basis of the Zeff . Also known as <em>effective nuclear charge.</em>

<em>Zeff: It is the net positive charge felt by the outermost electron by the nucleus.</em>

<em>The value of Zeff depends upon the shielding constant. More the shielding less will be the Zeff . Hence the size of the atom increases.</em>

Due to shielding the outermost electrons feel less pull of nucleus.

<em>The greater the Zeff , the smaller the radius of the atom.</em>

The formula used to calculate the atomic mass is :

r_{n}=\frac{52.9n^{2}}{Z}pm

Here "pm"= picometers

1 pm = 10^{-12}m

<u>The size of the smallest atom H-atom = 120 pm</u>

<u>The range of atoms = (30-300 pm)</u>

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2 years ago
If you repeat an experiment and the result are very different from the result you got the first time the next step would be to w
Bess [88]
You would want to make sure that you have controlled the variables properly, and if you determine that you did then you would repeat the experiment to be sure of the results.
4 0
3 years ago
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