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2 years ago

What is the value for (delta)G at 1000 K if (delta)H = -220 kJ/mol and (delta)S = -0.05 kJ/(molK)?

Chemistry

2 answers:

lesantik [10]2 years ago

8 0

Answer:

D. -170 kJ (apex)

tankabanditka [31]2 years ago

6 0

The system is isothermal, so we use the formula:
(delta)G = (delta)H - T (delta) S

Plugging in the given values:
(delta)G = -220 kJ/ mol - (1000K) (-0.05 kJ/mol K)
(delta)G = -170 kJ/mol

If we take a basis of 1 mol, the answer is
D. -170 kJ

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Calculate the freezing point of a solution containing 5.0 grams of KCl and 550.0 grams of water. The molal-freezing-point-depres

yulyashka [42]

<u>Answer:</u> The freezing point of solution is -0.454°C

<u>Explanation:</u>

Depression in freezing point is defined as the difference in the freezing point of pure solution and freezing point of solution.

The equation used to calculate depression in freezing point follows:

$\Delta T_f=\text{Freezing point of pure solution}-\text{Freezing point of solution}$

To calculate the depression in freezing point, we use the equation:

$\Delta T_f=iK_fm$

Or,

$\text{Freezing point of pure solution}-\text{Freezing point of solution}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ (in grams)}}$

where,

Freezing point of pure solution = 0°C

i = Vant hoff factor = 2

$K_f$ = molal freezing point elevation constant = 1.86°C/m

$m_{solute}$ = Given mass of solute (KCl) = 5.0 g

$M_{solute}$ = Molar mass of solute (KCl) = 74.55 g/mol

$W_{solvent}$ = Mass of solvent (water) = 550.0 g

Putting values in above equation, we get:

$0-\text{Freezing point of solution}=2\times 1.86^oC/m\times \frac{5\times 1000}{74.55g/mol\times 550}\\\\\text{Freezing point of solution}=-0.454^oC$

Hence, the freezing point of solution is -0.454°C

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2 years ago

A solution of phosphoric acid was made by dissolving 10.8 g of H3PO4 in 133.00 mL of water. The resulting volume was 137 mL. Cal

Nesterboy [21]

Answer:

Density is: 1.05 g/ml

Mole fraction solute: 0.015

Mole fraction solvent: 0.095

Molarity: 0.80 M

Molality: 0.82 m

Explanation:

A typical excersise of solution.

It is more confortable to make a table for this.

| masss | volume | mol

solute | | |

solvent | | |

solution | | |

Let's complete, what we have.

| masss | volume | mol

solute | 10.8g | |

solvent | | 133 mL |

solution | | 137 mL |

We can first, know how many moles are 10.8 g

Molar Mass H3PO4 = 97.99 g/mol

Mass / Molar mass = mol

10.8 g / 97.99 g/m = 0.110 mol

Density of water is 1 g/ml (it is a very knowly value)

From this data, we can know water mass, solvent.

Density = mass / volume

1 g/ml = mass / 133 mL

Mass = 133 g

We can also have the moles, by the molar mass of water 18 g/m

133 g / 18 g/m = 7.39 mol

| masss | volume | mol

solute | 10.8g | | 0.110 mol

solvent | 133g | 133 mL | 7.39 mol

solution | 143.8g | 137 mL | 7.50 mol

Mass of solution will be solute mass + solvent mass

Moles of solution will be solute moles + solvent moles

Now we can calculate everything.

Molarity means mol of solute in 1 L of solution. (mol/L)

We have to convert 137 mL in L (/1000)

0.137L so → 0.110 m / 0.137L = 0.80 M

Molality means mol of solute in 1kg of solvent.

We have to convert 133g in kg (/1000)

0.133 kg so → 0.110 m/0.133 kg = 0.82 m

Density is mass / volume

Solution density will be solution mass / solution volume

143.8 g/137 mL = 1.05 g/m

Molar fraction is : solute moles / total moles or solvent moles/total moles.

You can also (x 100%) to have a percent of them.

Remember sum of molar fraction = 1

Molar fraction of solute = 0.110 mol / 7.50mol = 0.015

Molar fraction of solvent = 7.39 mol / 7.50 mol = 0.985

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Answer:

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Why is it the principle about the relationship between mass and volume always true of substance, but not always true of mixtures

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Answer:

For pure substances, the mass and volume will always be the same or will always change the same way because all substance are the same throughout.

While for mixtures, you can have varying amount of each component therefore mass and volume will not change the same way for substances

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