Answer:
0.299 moles of PCl5
Explanation:
First form an equation based of given information: P4 + Cl2= 4PCl5
Next balance it: P4 + 10Cl2 = 4PCl5
Take your given value (53.0g of Cl2) and divide it by its molar mass to get moles of Cl2: 53.0g/70.906g = 0.747 moles Cl2
Then, multiply by the molar ratio (10Cl2 to 4PCl5): (0.747 x 4 mol PCl5)/10 mol Cl2 = 0.299 moles PCl5
Given:
K = 0.71 = Kp
The reaction of sulphur with oxygen is
S(s) + O2(g) ---> SO2(g)
initial Pressure 6.90 0
Change -x +x
Equilibrium 6.90-x x
Kp = pSO2 / pO2 = 0.71 = x / (6.90-x)
4.899 - 0.71x = x
4.899 = 1.71x
x = 2.86 atm = pressure of SO2 formed
temperature = 950 C = 950 + 273.15 K = 1223.15 K
Volume = 50 L
Let us calculate moles of SO2 formed using ideal gas equation as
PV = nRT
R = gas constant = 0.0821 L atm / mol K
putting other values
n = PV / RT = 2.86 X 50 / 1223.15 X 0.0821 = 1.42 moles
Moles of Sulphur required = 1.42 moles
Mass of sulphur required or consumed = moles X atomic mass of sulphur
mass of S = 1.42 X 32 = 45.57 grams or 0.04557 Kg of sulphur
Water is formed when this happens
(4) Zirconium
This element is often used in the chemical production field, and as implants due to its high chemical resistance and stability.