Answer:
Explanation:
<u>1) Reactants:</u>
The reactants are:
- <em>Molecular chlorine</em>: this is a gas diatomic molecule, i.e. Cl₂ (g)
- <em>Molecular fluorine</em>: this is also a gas diatomic molecule: F₂ (g)
<u>2) Stoichiometric coefficients:</u>
- <em>One volume of Cl₂ react with three volumes of F₂</em> means that the reaction is represented with coefficients 1 for Cl₂ and 3 for F₂. So, the reactant side of the chemical equation is:
Cl₂ (g) + 3F₂ (g) →
<u>3) Product:</u>
- It is said that the reaction yields <em>two volumes of a gaseous product;</em> then, a mass balance indicates that the two volumes must contain 2 parts of Cl and 6 parts of F. So, one volume must contain 1 part of Cl and 3 parts of F. That is easy to see in the complete chemical equation:
Cl₂ (g) + 3F₂ (g) → 2Cl F₃ (g)
As you see, that last equation si balanced: 2 atoms of Cl and 6 atoms of F on each side, and you conclude that the formula of the product is ClF₃.
This problem is describing a gas mixture whose mole fraction of hexane in nitrogen is 0.58 and which is being fed to a condenser at 75 °C and 3.0 atm, obtaining a product at 3.0 atm and 20 °C, so that the removed heat from the system is required.
In this case, it is recommended to write the enthalpy for each substance as follows:

Whereas the specific heat of liquid and gaseous n-hexane are about 200 J/(mol*K) and 160 J/(mol*K) respectively, its condensation enthalpy is 31.5 kJ/mol, boiling point is 69 °C and the specific heat of gaseous nitrogen is about 29.1 J/(mol*K) according to the NIST data tables and
and
are the mole fractions in the gaseous mixture. Next, we proceed to the calculation of both heat terms as shown below:

It is seen that the heat released by the nitrogen is neglectable in comparison to n-hexanes, however, a rigorous calculation is being presented. Then, we add the previously calculated enthalpies to compute the amount of heat that is removed by the condenser:

Finally we convert this result to kJ:

Learn more:
Answer:
6 Cl0 + 6 e- → 6 Cl-I (reduction)
2 Fe0 - 6 e- → 2 FeIII (oxidation)