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Lady bird [3.3K]
4 years ago
12

Please Answer! Help! Will Give Brainliest. Find Keq for a 3.0 L container with 1.2 moles of both NO2 and N2O4 initially and 0.38

M NO2 at equilibrium. 2NO2(g) ⇌ N2O4(g)
Chemistry
1 answer:
Nuetrik [128]4 years ago
6 0

Answer:

Kc → 41.9

Explanation:

This is the equilibrium:

2NO₂(g) ⇌ N₂O₄(g)

So the expression for Kc will be:

Kc = [N₂O₄] / [NO₂]²

We prospose the situations:

Initially we have 1.2 moles of NO₂ and N₂O₄

X amount has reacted. As stoichiometry is 2:1, we have produced x/2 of the product during the reaction

Finally In equilibrium we have, 0.38 NO₂

                2NO₂(g)     ⇌       N₂O₄(g)

Initially        1.2                        1.2

React            x                         x/2

Eq         (1.2 - x) = 0.38          1.2 + x/2

As we have [NO₂] in the equilibrium, we can determine x (the amount that has reacted) to solve and determine, the [N₂O₄] in the equilibrium

1.2-0.38 = x → 0.82

1.2 + 0.82/2 = 2.02 → [N₂O₄]

For Kc, we need Molar concentration, so we have to divide [N₂O₄] and [NO₂] by the volume

[N₂O₄] → 2.02 mol/3L = 0.673 M

[NO₂] → 0.38 mol/3L = 0.127 M

Now we can replace the Kc expression:

Kc →  [N₂O₄] / [NO₂]² → 0.673 / 0.127² = 41.9

Remember that Kc has no UNITS

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3 years ago
A chemist measures the energy change Delta H during the following
Ann [662]

Answer: 1) endothernic

2) Yes absorbed

Explanation:

Decomposition is a chemical reaction in which one reactant gives two or more than two products. All decomposition reactions are endothermic reactions as energy is absorbed to break the bonds.

Endothermic reactions are defined as the reactions in which energy of the product is greater than the energy of the reactants. The total energy is absorbed in the form of heat and \Delta H for the reaction comes out to be positive.

Exothermic reactions are defined as the reactions in which energy of the product is lesser than the energy of the reactants. The total energy is released in the form of heat and \Delta H for the reaction comes out to be negative.

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3 years ago
Using Gibbs Equation, dU=TdS-pdV show that (dS/dV) at a constant U =P/T. The reciprocal of (dS/dU)v = 1/T.
Troyanec [42]

Explanation:

dU=TdS-pdV (given)

To prove = 1) (\frac{dS}{dV})_U=\frac{P}{T} (at constant U)

2) (\frac{dS}{dU})_v=\frac{1}{T} (at constant V)

Solution: 1)

dU=TdS-PdV

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Solution: 2)

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c The K expression would be inverted.

Explanation:

Let's consider the following reaction at equilibrium.

      A(g) ⇄ 2 B(g)

colorless    dark colored

<em>(a) The cylinder should appear (color or colorless)</em>

At equilibrium, there is a mixture of A and B, so the cylinder should appear colored.

<em>(b) When the system is cooled, the cylinder's appearance becomes very light colored. Therefore, the reaction must be (endothermic or exothermic)</em>

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<em>c The K expression would be inverted.</em> TRUE. What was product before now is reactant and vice-versa.

<em>d The color of the cylinder would be darker.</em> FALSE. Changing the way the reaction is expressed has no effect on the equilibrium.

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