Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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Answer:
the difference in electronegativity is so large (2.04) that the bonding electrons spend almost all their time on the nitrogen atom.
Explanation:
Because calcium loses 2 electrons to become Ca2+, and nitrogen gains 3 electrons to become N3−, you need two calcium atoms and three nitrogen atoms in order to form a neutral compound.
Answer:
Mass = 2.89 g
Explanation:
Given data:
Mass of NH₄Cl = 8.939 g
Mass of Ca(OH)₂ = 7.48 g
Mass of ammonia produced = ?
Solution:
2NH₄Cl + Ca(OH)₂ → CaCl₂ + 2NH₃ + 2H₂O
Number of moles of NH₄Cl:
Number of moles = mass/molar mass
Number of moles = 8.939 g / 53.5 g/mol
Number of moles = 0.17 mol
Number of moles of Ca(OH)₂ :
Number of moles = mass/molar mass
Number of moles = 7.48 g / 74.1 g/mol
Number of moles = 0.10 mol
Now we will compare the moles of ammonia with both reactant.
NH₄Cl : NH₃
2 : 2
0.17 : 0.17
Ca(OH)₂ : NH₃
1 : 2
0.10 : 2/1×0.10 = 0.2 mol
Less number of moles of ammonia are produced by ammonium chloride it will act as limiting reactant.
Mass of ammonia:
Mass = number of moles × molar mass
Mass = 0.17 mol × 17 g/mol
Mass = 2.89 g
Because its only representing the most stable isotope of that element but its considered the atomic mass and not average atomic mass
