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Furkat [3]
3 years ago
6

When 2-heptyne was treated with aqueous sulfuric acid containing mercury(II) sulfate, two products, each having the molecular fo

rmula C7H14O, were obtained in approximately equal amounts. What are these two compounds?

Chemistry
1 answer:
xeze [42]3 years ago
3 0

Answer:

See explanation below

Explanation:

This is a reaction of alkyne hydration. We have aqueous sulfuric acid in HgSO4. This reagent is used to convert a alkyne into a ketone. The mechanism of reaction is taking place in 4 steps.

The first step is an electrophilic adition where the atom of Hydrogen that the acid provides, is added to the alkyne in the triple bond.

In this step, as Carbon 2 and Carbon 3, do not have any atom of hydrogen, the adition of this hydrogen could take place in either carbon 2 or carbon 3, that's why at the end you can have two products in equal amounts.

The second step is the adition of one molecule of water in the carbocation that appears in the previous step.

The third step, is an acid base equilibrium, where the hydrogen atom from the water that added to the heptene, is substracted (In this case by the conjugate base of the acid).

In this way, we will have an alcohol with a double bond. This is the enolic form of the molecule.

The final step is a tautomeric equilibrium, where the double bond of the C = C will pass to a double bond C = O forming a carbonile and therefore, a ketone.

If this was done in carbon 2 from step 1, you'll have the 2-heptanone. If it were on carbon 3, it will be the 3 - Heptanone.

Picture attached has the mechanism and products.

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Commercial concentrated aqueous ammonia is 28% nh3 by mass and has a density of 0.90 g/ml. what is the concentration of ammonia
patriot [66]

Answer:- 14.9 M

Solution:- Given commercial sample of ammonia is 28% by mass. Let's say we have 100 grams of the sample. Then mass of ammonia would be 28 grams.

Density of the solution is given as 0.90 grams per mL.

From the mass and density we could calculate the volume of the solution as:

100g(\frac{1mL}{0.90g})

= 111 mL

Let's convert the volume from mL to L as molarity is moles of solute per liter of solution.

111mL(\frac{1L}{1000mL})  

= 0.111 L

Now, we convert grams of ammonia to moles on dividing the grams by molar mass. Molar mass of ammonia is 17 gram per mole.

28g(\frac{1mole}{17g})

= 1.65 mole

To calculate the molarity we divide the moles of ammonia by the liters of solution:

molarity=\frac{1.65mole}{0.111L}

= 14.9 M

So, the molarity of the given commercial sample of ammonia is 14.9 M.

5 0
3 years ago
There are two open cans of soda on the table. One can was just taken from the refrigerator and the other was taken from the cupb
nika2105 [10]
I think the correct answer from the choices listed above is option C. The can <span>from the cupboard will lose carbon dioxide more quickly because it is warmer and gases are less soluble in warmer temperatures. </span> Solubility of gases is a strong function of temperature and as well as pressure.
5 0
3 years ago
Read 2 more answers
Please Help
rewona [7]

Answer:

The correct answer is - they can create genetic diversity as well and reproduce without mate when necessary.

Explanation:

Sexual reproduction provides an organism with genetic diversity and variation by the process and it required two mates and a longer time to pollination and fertilization and is used in normal conditions.

In case of a threat, such organisms use asexual reproduction to increase their number as in asexual reproduction no need of mate, an organism can grow and increase on its own it provides to not to exitinct.

7 0
3 years ago
How do you know what numbers in a chemical formula are significant
bulgar [2K]

Answer:

All the numbers in a chemical formula are significant, It is because the numbers in a chemical formula denote the number of different atoms present in the particular compound.

For example in H2SO4 there are 2 H 1 S and 4 O. This means 1 H2SO4 has 2 hydrogen 1 sulphur and 4 oxygen.

3 0
3 years ago
Estimate the enthalpy change for the combustion of one mole of acetylene, C2H2, to form carbon dioxide and water vapor. BE(C?H)
tia_tia [17]

Answer:

ΔH rxn =  -1010 kJ/molC₂H₂

Explanation:

To obtain the enthalpy change for a reaction from bond energies what we do is to make an inventory of the bonds broken and formed for the balanced chemical reaction:

C₂H₂ + 5/2O₂   ⇒   2CO₂ + H₂O

Bond Broken                                    Bonds Formed

2 C-H + 1 C≡C + 5/2 O=O                4C=O + 2 H-O

Enthalpy bonds broken:

2 mol (456 kJ/mol)+ 1 mol (962 kJ/mol) + 5/2 mol (499 kJ/mol)  =  3121.5 kJ

Enthalpy bond formed:

4 mol (802 kJ/mol) + 2 mol (462 kJ/mol) = 4132.0 kJ

ΔH rxn = H broken - H formed =  3121.5 kJ - 4132.0 kJ = - 1010  kJ (per mol C₂H₂ )

4 0
3 years ago
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