1st and 4th options are suitable answers, as these 2 changes are not exactly physical changes as it cant return back to original form and as well as its not cooling, so I feel its 1st and 4th options
The production of
is
. Converting mass into kg,
1 ton=907.185 kg, thus,

Thus, production of
will be
.
The specific volume of
is
.
Volume of
produced per day can be calculated as:

Putting the values,

Thus, volume of
produced per year will be:

Thus, in 4 year volume of
produced will be:

Answer:
Carbon dioxide as well as water are needed for photosynthesis.
Explanation: