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Andrej [43]
3 years ago
11

Could the structures below undergo a Fischer esterification reaction? Reaction scheme of benzoic acid and thionyl chloride to fo

rm an unknown product. No, the structures above cannot undergo a Fischer esterification reaction to form an ester. Yes, if the carboxylic acid is heated in the SOCl2 reagent and a small amount of H2SO4 is used as a catalyst.

Chemistry
1 answer:
Romashka-Z-Leto [24]3 years ago
4 0

Answer:

The correct answer is the first option. No, the structures above cannot undergo a Fischer esterification reaction to form an ester.

Explanation:

The reaction that will take place can be found in the attached file. The reaction does not require any catalyst and it cannot undergo a Fischer esterification reaction to form an ester.

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Answer:

pH = 1.32

Explanation:

                 H₂M + KOH ------------------------ HM⁻ + H₂O + K⁺

This problem involves a weak diprotic acid which we can solve by realizing they amount  to buffer solutions.  In the first  deprotonation if all the acid is not consumed we will have an equilibrium of a wak acid and its weak conjugate base. Lets see:

So first calculate the moles reacted and produced:

n H₂M = 0.864 g/mol x 1 mol/ 116.072 g  =  0.074 mol H₂M

54 mL x  1L / 1000 mL x 0. 0.276 moles/L = 0.015 mol KOH

it is clear that the maleic acid will not be completely consumed, hence treat it as an equilibrium problem of a buffer solution.

moles H₂M left = 0.074 - 0.015 = 0.059

moles HM⁻ produced = 0.015

Using the Henderson - Hasselbach equation to solve for pH:

ph = pKₐ + log ( HM⁻/ HA) = 1.92 + log ( 0.015 / 0.059) = 1.325

Notes: In the HH equation we used the moles of the species since the volume is the same and they will cancel out in the quotient.

For polyprotic acids the second or third deprotonation contribution to the pH when there is still unreacted acid ( Maleic in this case) unreacted.

           

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Two aircraft rivets, one iron and the other copper, are placed in a calorimeter that has an initial temperature of 20.°C. The da
Igoryamba

The heat will flow from Cu to Fe because Cu has higher temperature and has lower peak value .

Given ,

two aircraft rivets , one iron and the other copper , are placed in a calorimeter .

the initial temp of the calorimeter is 20 degC .

mass of iron = 30 g

initial temp of iron = 0 degC

Mass of copper = 20 g

initial temp of copper = 100 degC

Here copper has higher temp ,thus heat flow from Cu to Fe .

<h3>What is heat flow ?</h3>

Heat flow is the movement of heat from higher temperature to lower temperature .

<h3>What is calorimeter ?</h3>

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Learn more about calorimeter here :

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