Using a skeletal structure, give the structure corresponding to the name (s)−3−iodo−2−methylnonane.
1 answer:
Explanation:
For the given compound: (s)-3-iodo-2-methylnonane, only third carbon- atom (marked with red dot) is the chiral atom (as it is attached to 4 different substituents), so the configuration will be assigned to this C-atom only.
In assigning the configuration of this compound, the priorities are assigned based on their atomic masses. The lowest priority group ( that is Hydrogen) should lie on the vertical line. But here, it is lying on the horizontal line, so the configuration will be reversed.
The configuration coming out when H is on the horizontal line is R, but the actual configuration will be S.
The structure of the given organic compound is shown in the image attached.
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Here we have to get the of the reaction at 520 K temperature.
The of the reaction is 1.705 atm
We know the relation between and
is
, where
= The equilibrium constant of the reaction in terms of partial pressure,
= The equilibrium constant of the reaction in terms of concentration and N = number of moles of gaseous products - Number of moles of gaseous reactants.
Now in this reaction, PCl₃ + Cl₂ ⇄ PCl₅
Thus number of moles of gaseous product is 1, and number of moles of gaseous reactants are 2. Thus N = |1 - 2| = 1 mole
The given value of is 4.0×10⁻²
The molar gas constant, R = 0.082 L. Atm. mol⁻¹. K⁻¹ and temperature, T = 520 K.
On plugging the values in the equation we get,
Or, = 1.705 atm
Thus, the of the reaction is 1.705 atm