Answer:
CH₃CH₂CH₂COOH > CH₃CH₂COOH > ClCH₂CH₂COOH > ClCH₂COOH
Explanation:
Electron-withdrawing groups (EWGs) increase acidity by inductive removal of electrons from the carboxyl group.
Electron-donating groups (EDGs) decrease acidity by inductive donation of electrons to the carboxyl group.
- The closer the substituent is to the carboxyl group, the greater is its effect.
- The more substituents, the greater the effect.
- The effect tails off rapidly and is almost zero after about three C-C bonds.
CH₃CH₂-CH₂COOH — EDG — weakest — pKₐ = 4.82
CH₃-CH₂COOH — reference — pKₐ = 4.75
ClCH₂-CH₂COOH — EWG on β-carbon— stronger — pKₐ = 4.00
ClCH₂COOH — EWG on α-carbon — strongest — pKₐ = 2.87
There are several differences between<span> a </span>physical and chemical change<span> in matter or substances. A </span>physical change<span> in a substance doesn't </span>change<span> what the substance is. In a </span>chemical change<span> where there is a </span>chemical<span> reaction, a new substance is formed and energy is either given off or absorbed.</span>
Answer:
54 grams ammonium chloride and 40 grams sodium hydroxide
Explanation:
A buffer is a solution that contains either a weak acid and its salt or a weak base and its salt, the solution is resistant to changes in pH. This means that, a buffer is an aqueous solution of either a weak acid and its conjugate base or a weak base and its conjugate acid.
A Buffer is used to maintain a stable pH in a solution, buffers can neutralize small quantities of additional acid of base. For any buffer solution, there is always a working pH range and a set amount of acid or base that can be neutralized before the pH will change. The amount of acid or base that can be added to a buffer before changing its pH is called its buffer capacity.
A good buffer mixture is supposed to have about equal concentrations of its both components. It is a rule of thumb therefore, that a buffer solution has generally lost its usefulness when one component of the buffer pair is less than about 10% of the other component.
The implication of this is that the ammonium chloride and sodium hydroxide should be of approximately the same concentration. If the masses are dissolved as shown in the answer, then we will have 1molL-1 of each component of the buffer in accordance with the rule of thumb stated above.
Answer:
The answer to your question is: ΔH = -283 kJ/mol, first option
Explanation:
Reaction
CO + O₂ ⇒ CO₂
ΔH = ∑H products - ∑H products
ΔH = -393.5 - (-110.5 + 0)
ΔH = -393.5 + 110.5
ΔH = -283 kJ/mol
