2. What is the relationship between the scientific method and bias? Explain in detail.
1 answer:
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The conversion of 2 - butanol to 2 - nitrobutane involves conversion of 2 butanol to 2 - bromobutane and subsequently to 2 - nitrobutane.
In order to convert 2 - butanol to 2 - nitrobutane, an SN2 reaction is first carried out in which 2 - butanol is converted to 2 - bromobutane. This reaction proceeds with inversion of configuration at the chiral carbon as expected.
This product is subsequently reacted with silver nitrite in ethanol to yield 2 - nitrobutane along side silver bromide. Some alkyl nitrite is also produced as a by product. The components of the mixture are separated by fractional distillation. The scheme of the reaction is shown in the image attached to this answer. This reaction is only applied to primary and secondary alkyl halides.
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Answer:
The molar heat capacity at constant volume is 21.62 JK⁻¹mol⁻¹
The molar heat capacity at constant pressure is 29.93 JK⁻¹mol⁻¹
Explanation:
We can calculate the molar heat capacity at constant pressure from
Where is the molar heat capacity at constant pressure
is the heat capacity at constant pressure
and is the number of moles
Also is given by
Hence,
becomes
From the question,
= 229.0 J
= 3.00 mol
= 2.55 K
Hence,
becomes
29.93 JK⁻¹mol⁻¹
This is the molar heat capacity at constant pressure
For, the molar heat capacity at constant volume,
From the formula
Where is the molar heat capacity at constant volume
and is the gas constant (
= 8.314 JK⁻¹mol⁻¹)
Then,
21.62 JK⁻¹mol⁻¹
This is the molar heat capacity at constant volume