Answer:
4.79x10¹³s⁻¹
Explanation:
For a first order reaction, the graph of ln k against 1/K follows Arrhenius equation:
lnK = ln A - Ea/RT
<em>Where A is pre-exponential factor, Ea is activation energy, R gas constant and T is absolute temperature</em>
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If you graph ln k = y and 1/T = x:
y = lnA - Ea/R x
<em>Where the slope = -Ea/R</em>
<em>And the intercept = lnA</em>
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To solve the pre-exponential factor:
31.5 = lnA
e^31.5 =
<h3>4.79x10¹³s⁻¹</h3>
s⁻¹ because the reaction is first order.
<h3>What is the equilibrium constant?</h3>
The equilibrium constant shows the extent to which reactants are converted into products.
In this case, we must find the reaction quotient as follows;
Qc = [0.55]^2/[0.12] = 2.5
Since the Qc > Kc, it means that the reverse direction is favored in this reaction.
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The correct answer is 0.16138
<u>Solution:</u>
Percentage transmission (%T) of the sample = 15.6
Therefore, Absorbance (A) 2 – log (%T) = 2 – log (15.6) = 0.8069
<u>Use Beer’s law:</u>
A = ε*c*l where ε = molar absorptivity of the solution, c = concentration of the solution, and l = path length of the solution.
Given A = 0.8069 and l = 5.00 cm, we must have
<u>0.8069 = ε*c*(5.00 cm)</u>
ε*c = 0.16138 cm-1
For the next part, assume that ε*c remains constant and we have
A’ = ε*c*l’ where l = 1.00 cm.
Plug in values and write
A’ = (0.16138 cm-1)*(1.00 cm) = 0.16138
The ratio of the light intensity entering the sample to the light intensity exiting the sample at a particular wavelength is defined as the transmittance. Absorption and transmission are two related and different quantities used in spectroscopy. The main difference between absorption and transmission is that absorption measures how much incident light is absorbed as it travels through the material, while transmission measures how much light is transmitted.
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In fact, upwellings are common in areas where winds blow water away from the surface. In coastal areas, sometimes winds (called longshore winds) blow perpendicular to the land over the ocean, pushing the warm water away from the coast. This allows the cold water at the bottom to rise up and replace the warmer water.