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Natalija [7]
3 years ago
8

In the gas-phase reaction 2 A + B ⇌ 3 C + 2 D, it was found that, when 1.00 mol A, 2.00 mol B, and 1.00 mol D were mixed and all

owed to come to equilibrium at 25 °C, the resulting mixture contained 0.90 mol C at a total pressure of 1.00 bar. Calculate
(i) the mole fractions of each species at equilibrium,
(ii) K, and
(iii) Δrimage.
Chemistry
1 answer:
Naddik [55]3 years ago
3 0

Answer:

(i)The mole fractions are :

  • A=\frac{0.4}{4.3} \\=0.0930
  • B=\frac{1.4}{4.3} \\=0.3256
  • C=\frac{0.9}{4.3} \\=0.2093
  • D=\frac{1.6}{4.3} \\=0.3721

(ii)K=0.4508

(iii)ΔG = 1.974kJ

Explanation:

The given equation is :

2A+B⇄3C+2D

Let \alpha be the number of moles dissociated per mole of B

Thus ,

<em>The initial number of moles of :</em>

  • A=1
  • B=2
  • C=0
  • D=1

2A\\(1-2\alpha)     +  B\\2(1-\alpha)  ⇄  3C\\(3\alpha)   + 2D\\(1+2\alpha)

And finally the number of moles of C[tex] is 0.9Thus ,[tex]3\alpha=0.9\\\alpha=0.3[tex]The final number of moles of:[tex]A = 1-2\alpha=1-2*0.3=0.4mol[tex] [tex]B=2(1-\alpha)=2(1-0.3)=1.4mol[tex][tex]D=1+2\alpha=1+2*0.3=1.6mol[tex]Thus , total number of moles are : 0.4+1.4+0.9+1.6=4.3(i)The mole fractions are : [tex]A=\frac{0.4}{4.3} \\=0.0930

  • B=\frac{1.4}{4.3} \\=0.3256
  • C=\frac{0.9}{4.3} \\=0.2093
  • D=\frac{1.6}{4.3} \\=0.3721

(ii)

K=\frac{(P_C^3)(P_D^2)}{(P_A^2)(P_B)}

Where ,

P_A,P_B,P_C,P_D are the partial pressures of A,B,C,D respectively.

Total pressure = 1 bar .

∴

<em>P_A= 0.0930*1=0.0930</em>

<em>P_B= 0.3256*1=0.3256</em>

<em>P_C= 0.2093*1=0.2093</em>

<em>P_D= 0.3721*1=0.3721</em>

K=\frac{0.2093^3*0.3721^2}{0.0930^2*0.3256} \\K=0.4508

(iii)

ΔG=-RTlnK\\

ΔG = -8.314*(273+25)*ln(0.4508)\\=1973.96J\\=1.974kJ

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