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Kisachek [45]
3 years ago
7

Will water freeze at 5 degrees Celsius? Will it freeze at -5 degrees Celsius? Delta S for the freezing of water is -22.1 J/K and

the surroundings must absorb 6000J of heat for water to freeze.
I know the equation we use to solve for both temperatures is deltaS(univ)=deltaS(sys) + q(surr)/T.

I'm not sure what the universal delta S would be. Would the delta S for the system be the -22.1 J/K or will I have to convert? Also, is the q(surroundings) the 6000J or something else?

Does anyone have example problems to help me solve this, or general steps to take with these types of problems? I checked other problems in the textbook and the others are not like this one! Thank you in advance.
Chemistry
1 answer:
ElenaW [278]3 years ago
6 0
The water froze meaning you have to examine it
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Consider the following reaction:
iren [92.7K]

Answer:

A. ΔG° = 132.5 kJ

B. ΔG° = 13.69 kJ

C. ΔG° = -58.59 kJ

Explanation:

Let's consider the following reaction.

CaCO₃(s) → CaO(s) + CO₂(g)

We can calculate the standard enthalpy of the reaction (ΔH°) using the following expression.

ΔH° = ∑np . ΔH°f(p) - ∑nr . ΔH°f(r)

where,

n: moles

ΔH°f: standard enthalpy of formation

ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CaCO₃(s))

ΔH° = 1 mol × (-635.1 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1206.9 kJ/mol)

ΔH° = 178.3 kJ

We can calculate the standard entropy of the reaction (ΔS°) using the following expression.

ΔS° = ∑np . S°p - ∑nr . S°r

where,

S: standard entropy

ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)) - 1 mol × S°(CaCO₃(s))

ΔS° = 1 mol × (39.75 J/K.mol) + 1 mol × (213.74 J/K.mol) - 1 mol × (92.9 J/K.mol)

ΔS° = 160.6 J/K. = 0.1606 kJ/K.

We can calculate the standard Gibbs free energy of the reaction (ΔG°) using the following expression.

ΔG° = ΔH° - T.ΔS°

where,

T: absolute temperature

<h3>A. 285 K</h3>

ΔG° = ΔH° - T.ΔS°

ΔG° = 178.3 kJ - 285K × 0.1606 kJ/K = 132.5 kJ

<h3>B. 1025 K</h3>

ΔG° = ΔH° - T.ΔS°

ΔG° = 178.3 kJ - 1025K × 0.1606 kJ/K = 13.69 kJ

<h3>C. 1475 K</h3>

ΔG° = ΔH° - T.ΔS°

ΔG° = 178.3 kJ - 1475K × 0.1606 kJ/K = -58.59 kJ

5 0
4 years ago
Which statement best describes one way that plate tectonics causes change
Romashka-Z-Leto [24]

Answer: Plate tectonics was Wegener's theory that Earth's continents rest on sections of Earth's crust that drift together and apart over time; continental drift is a hypothesis describing how plate tectonics might happen.

 

Explanation: Tectonic plate movement is a long-term environmental change.

7 0
2 years ago
Iron has a density of 7.86 g/cm3 and a mass of 3.76 kg. calculate the volume
DaniilM [7]
Density = Mass / Volume

Input the values in their respective places and then use algebra to solve for volume.

Hope that helps.
7 0
3 years ago
1.What are pollen grain? 2. what is an embryo?<br>​
swat32

Answer: 2= baby being developed= embryo 1 i dont know sorry

Explanation:

3 0
4 years ago
Read 2 more answers
Solution of the Schrödinger wave equation for the hydrogen atom results in a set of functions (orbitals) that describe the behav
kvv77 [185]

Answer :

'n' specifies  → (B) The energy and average distance from the nucleus.

'l' specifies   → (C) The subshell orbital shape.

'ml' specifies → (A) The orbital orientation.

Explanation :

Principle Quantum Numbers : It describes the size of the orbital. It is represented by n. n = 1,2,3,4....

Azimuthal Quantum Number : It describes the shape of the orbital. It is represented as 'l'. The value of l ranges from 0 to (n-1). For l = 0,1,2,3... the orbitals are s, p, d, f...

Magnetic Quantum Number : It describes the orientation of the orbitals. It is represented as m_l. The value of this quantum number ranges from (-l\text{ to }+l). When l = 2, the value of

Spin Quantum number : It describes the direction of electron spin. This is represented as m_s. The value of this is +\frac{1}{2} for upward spin and -\frac{1}{2} for downward spin.

As per question we conclude that,

'n' specifies  → The energy and average distance from the nucleus.

'l' specifies   → The subshell orbital shape.

'ml' specifies → The orbital orientation.

5 0
3 years ago
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