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seropon [69]
3 years ago
10

A gas sample occupies a volume of 1.264 L when the temperature is 168.0 °C and the pressure is 946.6 torr. How many molecules ar

e in sample?
Chemistry
1 answer:
alukav5142 [94]3 years ago
5 0

Answer:

0.26×10²³ molecules

Explanation:

Given data:

Volume of gas = 1.264 L

Temperature = 168°C

Pressure = 946.6 torr

Number of molecules of gas = ?

Solution:

Temperature = 168°C (168+273= 441 K)

Pressure = 946.6 torr (946.6/760 = 1.25 atm)

Now we will determine the number of moles.

PV = nRT

P= Pressure

V = volume

n = number of moles

R = general gas constant = 0.0821 atm.L/ mol.K  

T = temperature in kelvin

n = PV/RT

n = 1.25  atm ×1.264 L / 0.0821 atm.L/ mol.K   ×441 K

n = 1.58 /36.21 /mol

n = 0.044 mol

Now we will calculate the number of molecules by using Avogadro number.

1 mol = 6.022×10²³ molecules

0.044 mol × 6.022×10²³ molecules/ 1mol

0.26×10²³ molecules

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Learn how changes in binding free energy affect binding and the ratio of unbound and bound molecules.
Delvig [45]

C)[D]/[ED] = 5.20

D)[D]/[ED] = 5.20

E)[D']_T = 1.495* 10 ^-7 M

F)[D'] / [ED']  = 0.0579

Explanation:

E = 250 nM =2.5* 10 ^-7 mol/L , T=298.15 K

Dissociation constant of K_D = 1.3 μM (1.3 *10 ^-6 M)

E + D ⇄ ED → K_a = [ED] / [D][E]   (association constant)

ED ⇄ E + D → K_D = [E][D] / [ED]  (dissociation constant)

C)

[E] =2.5*10^-7 mol/L

K_D = 1.3* 10^-6 M

K_D = [E][D] / [ED] → [D]/[ED] = K_D / [E]

= [D]/[ED] = 1.3* 10 ^-6 / 2.5 *10^-7

= 13/25 * 10

=130/25 = 5.20

[D]/[ED] = 5.20

D)

ΔG =RTln Kd

ΔG_2 for E and D = 1.987 * 298.15 * ln 1.3*10^-6

ΔG_2 592.454 * [ln 1.3 +ln 10^-6]

ΔG_1 = 592.424 [0.2623 - 13.8155]

ΔG_2 = -592.424 * 13.553

ΔG_1 = -8184.633 cal/ mol

ΔG_1 = -8184.633  * 4.18 J/mol = -34244.508 J?mol

ΔG_1 = -34.245 KL/mol

so, ΔG_2 = ΔG_1 - 10.5 KJ/mol

ΔG_2 = -34.245 - 10.5

ΔG_2 = -44.745KJ / mol

ΔG_2 =RT ln K_D

-44.745 *10^3

=8.314 *298.15 lnK_D

lnK_D' = - 44745 / 2478.81 g

ln K_D' = -18.051

K_D' = -18.051

K_D' = e^-18.051

[D]/[ED] = 5.20

E)

[E] = 2.5* 10 ^-7 mol/ L = a

K_D' = [E][D] / [ED']                                  E +D' → ED'

K_D' = a/2(x-(a/2) / (a/2)

KD' = x - a/2

=2.447 *10^-8 = (2.5/2) * 10^-7

x=2.447 * 10^-8 + 1.25 * 10^-7

x = 2.447 *10^-8 + 1.25 * 10 ^-7

x= 10^-7 [1.25 + 0.2447]

x = 1.4947 * 10^-7

[D']_T = 1.495* 10 ^-7 M

F)

K_D' = [E][D'] / [ED']

[D'] / [ED'] = KD' / [E]

[D'] / [ED'] = 1.447 *10^-8 / 2.5* 10^-7

[D'] / [ED'] = 0.5788 * 10^-1

[D'] / [ED']  = 0.0579

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                           Bromic Acid  =  HBrO₃

                           Perbromic Acid  =  HBrO₄

When these acids are converted to their conjugate bases their names are as follow,

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                           Perbromate  =  ⁻OBrO₃

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