The equilibrium constant has been estimated to be 0.12 at 25 °C. If you had originally placed 0.069 mol of cyclohexane in a 2.8
1 answer:
Answer: Concentrations of cyclohexane and methylcyclopentane at equilibrium are 0.0223 M and 0.0027 M respectively
Explanation:
Moles of cyclohexane = 0.069 mole
Volume of solution = 2.8 L
Initial concentration of cyclohexane =
The given balanced equilibrium reaction is,
cyclohexane ⇔ methylcyclopentane
Initial conc. 0.025 M 0
At eqm. conc. (0.025-x)M (x) M
The expression for equilibrium constant for this reaction will be,
K= methylcyclopentane / cyclohexane
Now put all the given values in this expression, we get :
By solving the term 'x', we get :
x = 0.0027
Concentration of cyclohexane at equilibrium = (0.025-x ) M = (0.025-0.0027) M = 0.0223 M
Concentration of methylcyclopentane at equilibrium = (x ) M = (0.0027) M
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Considering the definition of STP conditions and Avogadro's number, the number of molecules of gas present in 2.24 L is 6.023×10²² molecules.
<h3>Definition of STP condition</h3>The STP conditions refer to the standard temperature and pressure. Pressure values at 1 atmosphere and temperature at 0 ° C are used and are reference values for gases. And in these conditions 1 mole of any gas occupies an approximate volume of 22.4 liters.
<h3>Definition of Avogadro's number</h3>Avogadro's Number or Avogadro's Constant is called the number of particles that make up a substance (usually atoms or molecules) and that can be found in the amount of one mole of said substance. Its value is 6.023×10²³ particles per mole. Avogadro's number applies to any substance.
<h3>Amount of molecules of carbon dioxide gas</h3>At STP, 2.24 L of carbon dioxide gas is collected. So, you can apply the following rule of three: if by definition of STP conditions 22.4 L are occupied by 1 mole of carbon dioxide gas, 2.24 L are occupied by how many moles of carbon dioxide gas?
amount of moles of carbon dioxide gas= 0.1 moles
Finally, 0.1 moles of carbon dioxide gas are collected.
Then you can apply the following rule of three, considering the Avogadro's number: If 1 mole of carbon dioxide gas contains 6.023×10²³ molecules, 0.1 mole of carbon dioxide gas contains how many molecules?
amount of molecules of carbon dioxide gas= (6.023×10²³ molecules × 0.1 moles)÷1 mole
amount of molecules of carbon dioxide gas=6.023×10²² molecules
Finally, the number of molecules of gas present in 2.24 L is 6.023×10²² molecules.
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STP conditions:
Avogadro's Number:
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