Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-![\int\limits^a_b {P} \, dV](https://tex.z-dn.net/?f=%5Cint%5Climits%5Ea_b%20%7BP%7D%20%5C%2C%20dV)
a=![v_2\\](https://tex.z-dn.net/?f=v_2%5C%5C)
b=![v_1](https://tex.z-dn.net/?f=v_1)
from virial equation
![\frac{PV}{RT}=z=1+\frac{B}{V}+\frac{C}{V^2}\\ \\P=RT(1+\frac{B}{V} +\frac{C}{V^2})\frac{1}{V}\\](https://tex.z-dn.net/?f=%5Cfrac%7BPV%7D%7BRT%7D%3Dz%3D1%2B%5Cfrac%7BB%7D%7BV%7D%2B%5Cfrac%7BC%7D%7BV%5E2%7D%5C%5C%20%20%20%5C%5CP%3DRT%281%2B%5Cfrac%7BB%7D%7BV%7D%20%2B%5Cfrac%7BC%7D%7BV%5E2%7D%29%5Cfrac%7B1%7D%7BV%7D%5C%5C)
And
![W=-\int\limits^a_b {RT(1+\frac{B}{V} +\frac{C}{V^2}\frac{1}{V} } \, dV](https://tex.z-dn.net/?f=W%3D-%5Cint%5Climits%5Ea_b%20%7BRT%281%2B%5Cfrac%7BB%7D%7BV%7D%20%2B%5Cfrac%7BC%7D%7BV%5E2%7D%5Cfrac%7B1%7D%7BV%7D%20%20%7D%20%5C%2C%20dV)
a=![v_2\\](https://tex.z-dn.net/?f=v_2%5C%5C)
b=![v_1](https://tex.z-dn.net/?f=v_1)
Now calculate V1 and V2 at given condition
![\frac{P1V1}{RT} = 1+\frac{B}{v_1} +\frac{C}{v_1^2}](https://tex.z-dn.net/?f=%5Cfrac%7BP1V1%7D%7BRT%7D%20%3D%201%2B%5Cfrac%7BB%7D%7Bv_1%7D%20%2B%5Cfrac%7BC%7D%7Bv_1%5E2%7D)
Substitute given values
= 1 x 10^5 , T = 373.15 and given values of coefficients we get
![10^5(v_1)/8.314*373.15=1-242.5/v_1+25200/v_1^2](https://tex.z-dn.net/?f=10%5E5%28v_1%29%2F8.314%2A373.15%3D1-242.5%2Fv_1%2B25200%2Fv_1%5E2)
Solve for V1 by iterative or alternative cubic equation solver we get
![v_1=30780 cm^3/mol](https://tex.z-dn.net/?f=v_1%3D30780%20cm%5E3%2Fmol)
Similarly solve for state 2 at P2 = 50 bar we get
![v_1=241.33 cm^3/mol](https://tex.z-dn.net/?f=v_1%3D241.33%20cm%5E3%2Fmol)
Now
![W=-\int\limits^a_b {RT(1+\frac{B}{V} +\frac{C}{V^2}\frac{1}{V} } \, dV](https://tex.z-dn.net/?f=W%3D-%5Cint%5Climits%5Ea_b%20%7BRT%281%2B%5Cfrac%7BB%7D%7BV%7D%20%2B%5Cfrac%7BC%7D%7BV%5E2%7D%5Cfrac%7B1%7D%7BV%7D%20%20%7D%20%5C%2C%20dV)
a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is
![W=-\int\limits^a_b {P(RT(-1/p^2+0+C')} \, dP](https://tex.z-dn.net/?f=W%3D-%5Cint%5Climits%5Ea_b%20%7BP%28RT%28-1%2Fp%5E2%2B0%2BC%27%29%7D%20%5C%2C%20dP)
a=![v_2\\](https://tex.z-dn.net/?f=v_2%5C%5C)
b=![v_1](https://tex.z-dn.net/?f=v_1)
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
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Explanation:
Answer:
investment 10 years from now is $1,238,000
.
Explanation:
given data
sum = $500,000
rate = 12% =0.12
total time = 10 year
solution
as present value After 2 years from now is $500,000
so time period is now = 8 year ( 10 - 2 )
so we apply future value formula that is
Future value = present value ×
............1
put here value we get
Future value = $500,000 ×
Future value = $500,000 × 2.476
Future value = $1,238,000
so investment 10 years from now is $1,238,000
.
Answer:
Water enters a centrifugal pump axially at atmospheric pressure at a rate of 0.12 m3/s and at a velocity of 7 m/s, and leaves in the normal direction along the pump casing, as shown in Fig. PI3-39. Determine the force acting on the shaft (which is also the force acting on the bearing of the shaft) in the axial direction.
Step-by-step solution:
Step 1 of 5
Given data:-
The velocity of water is .
The water flow rate is.
Answer:
# Program is written in Python Programming Language
# Comments are used for explanatory purpose
# Program starts here
# Accept input
Steps = input (Number of Steps: ")
# Calculate distance
distance = float(2000) * float(steps)
#Print Formatted Result
print('%0.2f' % distance)
# End of Program
.--------
The above program converts number of steps to miles.
At line 5, the number of steps is inputted and stored in variable named Steps.
At line 6, the number of miles is calculated by multiplying 2000 by the content of variable Steps
The result is printed at line 8