The enthalpy change of the reaction when sodium hydroxide and sulfuric acid react can be calculated using the mass of solution, temperature change, and specific heat of water.
The balanced chemical equation for the reaction can be represented as,
![H_{2}SO_{4}(aq) + 2NaOH (aq) ----> Na_{2}SO_{4}(aq) + 2H_{2}O(l)](https://tex.z-dn.net/?f=%20H_%7B2%7DSO_%7B4%7D%28aq%29%20%2B%202NaOH%20%28aq%29%20----%3E%20Na_%7B2%7DSO_%7B4%7D%28aq%29%20%2B%202H_%7B2%7DO%28l%29%20%20%20%20%20)
Given volume of the solution = 101.2 mL + 50.6 mL = 151.8 mL
Heat of the reaction, q =
Δ![T](https://tex.z-dn.net/?f=%20T%20)
m is mass of the solution = 151.8 mL * ![\frac{1 g}{1 mL} = 151.8 g](https://tex.z-dn.net/?f=%20%5Cfrac%7B1%20g%7D%7B1%20mL%7D%20%3D%20151.8%20g%20%20)
C is the specific heat of solution = 4.18 ![\frac{J}{g. ^{0}C}](https://tex.z-dn.net/?f=%20%5Cfrac%7BJ%7D%7Bg.%20%5E%7B0%7DC%7D%20%20%20)
ΔT is the temperature change = ![31.50^{0}C - 21.45^{0}C = 10.05^{0}C](https://tex.z-dn.net/?f=%2031.50%5E%7B0%7DC%20-%2021.45%5E%7B0%7DC%20%3D%2010.05%5E%7B0%7DC%20%20)
q = ![151.8 g (4.18 \frac{J}{g ^{0}C})(10.05^{0}C) = 6377 J](https://tex.z-dn.net/?f=%20151.8%20g%20%284.18%20%5Cfrac%7BJ%7D%7Bg%20%5E%7B0%7DC%7D%29%2810.05%5E%7B0%7DC%29%20%3D%206377%20J%20)
Moles of NaOH =
NaOH
Moles of
= ![50.6 mL * \frac{1 L}{1000 mL} * \frac{1.0 mol}{1 L} = 0.0506 mol H_{2}SO_{4}](https://tex.z-dn.net/?f=%2050.6%20mL%20%2A%20%5Cfrac%7B1%20L%7D%7B1000%20mL%7D%20%2A%20%5Cfrac%7B1.0%20mol%7D%7B1%20L%7D%20%3D%200.0506%20mol%20H_%7B2%7DSO_%7B4%7D%20%20%20)
Enthalpy of the reaction = ![\frac{6377 J*\frac{1kJ}{1000J}}{0.0506 mol} = 126 kJ/mol](https://tex.z-dn.net/?f=%20%5Cfrac%7B6377%20J%2A%5Cfrac%7B1kJ%7D%7B1000J%7D%7D%7B0.0506%20mol%7D%20%3D%20126%20kJ%2Fmol%20)
Answer:
<h3>The answer is 7.85 g/mL</h3>
Explanation:
The density of a substance can be found by using the formula
![density = \frac{mass}{volume} \\](https://tex.z-dn.net/?f=density%20%3D%20%20%5Cfrac%7Bmass%7D%7Bvolume%7D%20%20%5C%5C%20)
volume = final volume of water - initial volume of water
volume = 13.91 - 12 = 1.91 mL
We have
![density = \frac{15}{1.91} \\ = 7.853403141...](https://tex.z-dn.net/?f=density%20%3D%20%20%5Cfrac%7B15%7D%7B1.91%7D%20%20%5C%5C%20%20%3D%207.853403141...)
We have the final answer as
<h3>7.85 g/mL</h3>
Hope this helps you
Answer:
48%
Explanation:
Based on Gay-Lussac's law, the pressure is directly proportional to the temperature. To solve this question we must assume the temperature increases and all CO2 remains without reaction. The equation is:
P1T2 = P2T1
<em>Where Pis pressure and T absolute temperature of 1, initial state and 2, final state of the gas:</em>
P1 = 10.0atm
T2 = 1420K
P2 = ?
T1 = 730K
P2 = 10.0atm*1420K / 730K
P2 = 19.45 atm
The CO2 reacts as follows:
2CO2 → 2CO+ O2
Where 2 moles of gas react producing 3 moles of gas
Assuming the 100% of CO2 react, the pressure will be:
19.45atm * (3mol / 2mol) = 29.175atm
As the pressure rises just to 24.1atm the moles that react are:
24.1atm * (2mol / 19.45atm) = 2.48 moles of gas are present
The increase in moles is of 0.48 moles, a 100% express an increase of 1mol. The mole percent that descomposes is:
0.48mol / 1mol * 100 = 48%