Answer: See below
Explanation:
1. a) 0.15 moles calcium carbonate (15g/100g/mole)
b) 0.15 moles CaO (molar ratio of CaO to CaCO3 is 1:1)
c) 8.4 grams CaO (0.15 moles)*(56 grams/mole)
2. a) 0.274 moles Na2O (17g/62 grams/mole)
b) 46.6 grams NaNO3 (2 moles NaNO3/1 mole Na2O)*(0.274 moles Na2O)*(85 g/mole NaNO3)
Answer:
3) NaCl.
Explanation:
<em>∵ ΔTf = iKf.m</em>
where, <em>i</em> is the van 't Hoff factor.
<em>Kf </em>is the molal depression freezing constant.
<em>m</em> is the molality of the solute.
<em>The van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass. </em>
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- For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1.
<em>So, for sugar: i = 1.</em>
<em>∴ ΔTf for sugar = iKf.m = (1)(Kf)(2.0 m) = 2 Kf.</em>
<em></em>
- For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance.
For NaCl, it is electrolyte compound which dissociates to Na⁺ and Cl⁻.
<em>So, i for NaCl = 2.</em>
<em>∴ ΔTf for NaCl = iKf.m = (2)(Kf)(1.0 m) = 2 Kf.</em>
<em></em>
<em>So, the right choice is: 3) NaCl.</em>
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