Using the idea that reactions occur as a result of collisions between particles, explain why reaction rates depend on the concen
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Answer:
a) ΔGrxn = 6.7 kJ/mol
b) K = 0.066
c) PO2 = 0.16 atm
Explanation:
a) The reaction is:
M₂O₃ = 2M + 3/2O₂
The expression for Gibbs energy is:
ΔGrxn = ∑Gproducts - ∑Greactants
Where
M₂O₃ = -6.7 kJ/mol
M = 0
O₂ = 0
b) To calculate the constant we have the following expression:
Where
ΔGrxn = 6.7 kJ/mol = 6700 J/mol
T = 298 K
R = 8.314 J/mol K
c) The equilibrium pressure of O₂ over M is:
Answer:
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- <u>0.456M</u>
Explanation:
<u>1. Balanced molecular equation</u>
<u>2. Mole ratio</u>
<u>3. Moles of HNO₃</u>
- Number of moles = Molarity × Volume in liters
- n = 0.600M × 0.0100 liter = 0.00600 mol HNO₃
<u>4. Moles Ba(OH)₂</u>
- n = 0.700M × 0.0310 liter = 0.0217 mol
<u>5. Limiting reactant</u>
Actual ratio:
Since the ratio of the moles of HNO₃ available to the moles of Ba(OH)₂ available is less than the theoretical mole ratio, HNO₃ is the limiting reactant.
Thus, 0.006 moles of HNO₃ will react completely with 0.003 moles of Ba(OH)₂ and 0.0217 - 0.003 = 0.0187 moles will be left over.
<u>6. Final molarity of Ba(OH)₂</u>
- Molarity = number of moles / volume in liters
- Molarity = 0.0187 mol / (0.0100 + 0.0031) liter = 0.456M