Answer:
Initially the function is symmetric with respect to the axis of the one dimensional box. In the final state it is also symmetrical, however you can envision a snapshot of the system as the light field is interacting with the wave-function wherein a node begins to develop as is shown in the middle and the wave function is evolving from the initial to final state. Now consider that the electron density during process is the square of the wave function:
Electron density during transition
As can be seen in the initial and final states the electron density is symmetrically distributed with respect to the axis of the box. However with the field on, the electron density is not symmetrically distributed and a transitory dipole moment can be present. To relate back to real molecules think of each of those orbitals as a linear combination of atomic orbitals. One important factor is the symmetry. But there may be one other factor that will be just as important as symmetry. If you treat orbital 1 as a linear combination over n orbitals and orbital 2 as a linear combinations of orbitals as well, there will be a spatial over lap between the orbital in the ground state and the orbital in the excited state. If there is no spatial overlap between the ground state and excited state orbitals there will be no transition dipole moment. However, if the electrons are in the same place spatially, a large transition dipole moment will result.
Explanation:
CH3OH and CH3CH2CH2OH will easily dissolve in water based on polarity not on size.
<h3>What is Polarity ?</h3>
In chemistry, polarity describes the type of bonds that exist between atoms. Atoms share electrons when they join forces to form chemical bonds. When one of the atoms applies a stronger attractive force to the bond's electrons, a polar molecule is created.
- For instance, the chlorine atom is slightly negatively charged while the hydrogen atom in hydrogen chloride is slightly positively charged.
- Water is polar due to its form even though its molecules have no net charge. The molecule's hydrogen ends are positive, and its oxygen ends are negative. Water molecules are drawn to other polar molecules and to one another as a result.
Learn more about Polarity here:
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