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Butoxors [25]
3 years ago
9

Nickel and carbon monoxide react to form nickel carbonyl, like this: (s)(g)(g) At a certain temperature, a chemist finds that a

reaction vessel containing a mixture of nickel, carbon monoxide, and nickel carbonyl at equilibrium has the following composition: compound amount
Calculate the value of the equilibrium constant
Chemistry
1 answer:
horsena [70]3 years ago
4 0

The question is incomplete, here is the complete question:

Nickel and carbon monoxide react to form nickel carbonyl, like this:

Ni(s)+4CO(g)\rightarrow Ni(CO)_4(g)

At a certain temperature, a chemist finds that a 2.6 L reaction vessel containing a mixture of nickel, carbon monoxide, and nickel carbonyl at equilibrium has the following composition:

Compound            Amount

     Ni                        12.7 g

   CO                        1.98 g

Ni(CO)_4                  0.597 g

Calculate the value of the equilibrium constant.

<u>Answer:</u> The value of equilibrium constant for the reaction is 2448.1

<u>Explanation:</u>

We are given:

Mass of nickel = 12.7 g

Mass of CO = 1.98 g

Mass of Ni(CO)_4 = 0.597 g

Volume of container = 2.6 L

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Given mass of solute}}{\text{Molar mass of solute}\times \text{Volume of solution (in L)}}

\text{Equilibrium concentration of nickel}=\frac{12.7}{58.7\times 2.6}=0.083M

\text{Equilibrium concentration of CO}=\frac{1.98}{28\times 2.6}=0.0272M

\text{Equilibrium concentration of }Ni(CO)_4=\frac{0.597}{170.73\times 2.6}=0.00134M

For the given chemical reaction:

Ni(s)+4CO(g)\rightarrow Ni(CO)_4(g)

The expression of equilibrium constant for the reaction:

K_{eq}=\frac{[Ni(CO)_4]}{[CO]^4}

Concentrations of pure solids and pure liquids are taken as 1 in equilibrium constant expression.

Putting values in above expression, we get:

K_{eq}=\frac{0.00134}{(0.0272)^4}\\\\K_{eq}=2448.1

Hence, the value of equilibrium constant for the reaction is 2448.1

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2 years ago
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xeze [42]
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Answer:

Following are the answer to this question:

Explanation:

The value of pH solution is =5.17 So, the p^{OH}:

p^{OH}=14-56.17

      =8.823

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convert into the liter= 0.040L

The value of the concentrated NH_{3} =0.10 M

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convert into the liter= 0.050L

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The volume of the H_{2}So_{4}= 30 ml

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The value of concentrated H_2So_4=0.05 M

Calculating total volume=(0.40+0.050+0.030)

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calculating the new concentrated value of NH_4Cl= \frac{0.050\times 0.10}{0.120}= 0.04166 \ Mcalculating the new concentrated value of H_2So_4= \frac{0.030\times 0.05}{0.120}= 0.0125 \ M when 1 mol H_2So_4 produced 2 mols H^{+} so, 0.0125 in H_2So_4produced:

=4 \times (2 \times 0.0125) \ mol H^{+}\\\\= 0.025 mol H^{+}

create the ICE table:    

NH_3    \ \ \ \ \ \ \ \     + H^{+}  \ \ \ \ \ \ \longrightarrow NH_4^{+}                    

I (m)       0.033(m)            0.025                       0.04166

C            -0.025                 -0.025                       + 0.025  

E            8.3\times 10^{-3}     0                    0.0667

now calculating pH:

when ph= 8.83:

P^{H}= p^{kb}|+ \log\frac{[NH_4^{+}]}{[NH_3]}\\\\8.83=p^{kb}+\log\frac{0.0667}{8.3 \times 10^{-3}}\\\\p^{kb}=8.83-0.9069\\\\ \ \ \ =7.7231 \\\\\ The P^{kb} \ for \ NH_3 \ is =7.7231\\\\\ The P^{kb} \ for N^{+}H_4=14-7.7231\\\\\ \ \ \ \ \ =6.2769

5 0
3 years ago
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