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oee [108]
3 years ago
7

13) Methane (CH4) combines with oxygen according to the balanced equation below. What is the limiting reactant if 25.0 g of CH4

combines with 50.0 g of O2? CH4 + 2 O2 → CO2 + 2 H2O moles CH4 moles O2 moles O2 needed to react with given amount of CH4 limiting reactant ("methane" or "oxygen")
Chemistry
1 answer:
marissa [1.9K]3 years ago
8 0

Answer:

Limiting reactant: Oxygen O_2

Explanation:

First write the balanced chemical equation:

CH_4 + 2 O_2 \rightarrow CO_2 + 2 H_2O

mole=\frac{given\, mass}{molecular\, mass}

given mass of methane =25g

molecular mass of methane=16g/mol

mole=1.5625mol

given mass of oxygen=50

molar mass of oxygen=32g/mol

mole=1.5625mol

from the above balanced equation it is clearly that,

1 mole of methane needs 2 moles of oxygen for complete reaction

Therefore,

1.5625 moles of methane needs 3.125 moles of oxygen for complete reaction but we  have only 1.5625 moles of oxygen,

hence,

oxygen will be the  limiting reactant and methane will be the excess reactant

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Using the molecular orbital model to describe the bond- ing in F2????, F2, and F2????, predict the bond orders and the relative
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Answer: F2 : bond order= 1.0

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F2- : bond order = 0.5

Explanation:

1. Starting with F2+

The configuration gives;

F2+ = 9F = 1S2.2S2.2P5

= 9F+ = 1S2.2S2.2P4 (this shows it gives out an electron)

Electronic configuration = σ 1S2σ*1S2σ2S2σ*2S2σ2Pz2 π2Px2 = π2Py2 π*2Px2 = π*2Py1

The number of Electrons = (9*2) – 1 = 18 -1 = 17

Bonding electrons (Nb) = 10

Antibonding electrons (Na) = 7

Bond order = (10-7)/2 = 3/2 = 1.5

Number of unpaired electrons = 1

2. Starting with F2

The configuration gives;

F2 = 9F = 1S2.2S2.2P5

9F = 1S2.2S2.2P5 (this shows no loss of an electron)

Electronic configuration = σ 1S2σ*1S2σ2S2σ*2S2σ2Pz2 π2Px2 = π2Py2 π*2Px2 = π*2Py2

The number of Electrons = (9*2) = 18 electrons

Bonding electrons (Nb) = 10

Antibonding electrons (Na) = 8

Bond order = (10-8)/2 = 2/2 = 1.0

Number of unpaired electrons = 0

3. Starting with F2-

The configuration gives;

F2- = 9F = 1S2.2S2.2P5

10F--= 1S2.2S2.2P6 (this shows an addition of an electron)

Electronic configuration = σ 1S2σ*1S2σ2S2σ*2S2σ2Pz2 π2Px2 = π2Py2 π*2Px2 = π*2Py2 σ*2Pz

The number of Electrons = (9*2) + 1 = 19 electrons

Bonding electrons (Nb) = 10

Antibonding electrons (Na) = 9

Bond order = (10-9)/2 = 1/2 = 0.5

Number of unpaired electrons = 1

To get the order of bond as well as length, we know that;

Bond order directly proportional to 1/ Bond length

Therefore the Ascending Bond length = F2+ ˂ F2 ˂ F2-

3 0
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