Decrire l ebullition de l eau

Aquafers are bodies of water found above ground with thriving ecosystems.<br> O True<br> O False

BaLLatris [955]

Answer:

true

Explanation:

8 0

2 years ago

Be sure to answer all parts. Styrene is produced by catalytic dehydrogenation of ethylbenzene at high temperature in the presenc

svlad2 [7]

Answer:

a) ΔHºrxn = 116.3 kJ, ΔGºrxn = 82.8 kJ, ΔSºrxn = 0.113 kJ/K

b) At 753.55 ºC or higher

c )ΔG = 1.8 x 10⁴ J

K = 8.2 x 10⁻²

Explanation:

a) C6H5−CH2CH3 ⇒ C6H5−CH=CH2 + H₂

ΔHf kJ/mol -12.5 103.8 0

ΔGºf kJ/K 119.7 202.5 0

Sº J/mol 255 238 130.6*

Note: This value was not given in our question, but is necessary and can be found in standard handbooks.

Using Hess law to calculate ΔHºrxn we have

ΔHºrxn = ΔHfº C6H5−CH=CH2 + ΔHfº H₂ - ΔHºfC6H5−CH2CH3

ΔHºrxn = 103.8 kJ + 0 kJ - (-12.5 kJ)

ΔHºrxn = 116.3 kJ

Similarly,

ΔGrxn = ΔGºf C6H5−CH=CH2 + ΔGºfH₂ - ΔGºfC6H5CH2CH3

ΔGºrxn= 202.5 kJ + 0 kJ - 119.7 kJ = 82.8 kJ

ΔSºrxn = 238 J/mol + 130.6 J/mol -255 J/K = 113.6 J/K = 0.113 kJ/K

b) The temperature at which the reaction is spontaneous or feasible occurs when ΔG becomes negative and using

ΔGrxn = ΔHrxn -TΔS

we see that will happen when the term TΔS becomes greater than ΔHrxn since ΔS is positive , and so to sollve for T we will make ΔGrxn equal to zero and solve for T. Notice here we will make the assumption that ΔºHrxn and ΔSºrxn remain constant at the higher temperature and will equal the values previously calculated for them. Although this assumption is not entirely correct, it can be used.

0 = 116 kJ -T (0.113 kJ/K)

T = 1026.5 K = (1026.55 - 273 ) ºC = 753.55 ºC

c) Again we will use

ΔGrxn = ΔHrxn -TΔS

to calculate ΔGrxn with the assumption that ΔHº and ΔSºremain constant.

ΔG = 116.3 kJ - (600+273 K) x 0.113 kJ/K = 116.3 kJ - 873 K x 0.113 kJ/K

ΔG = 116.3 kJ - 98.6 kJ = 17.65 kJ = 1.8 x 10⁴ J ( Note the kJ are converted to J to necessary for the next part of the problem )

Now for solving for K, the equation to use is

ΔG = -RTlnK and solve for K

- ΔG / RT = lnK ∴ K = exp (- ΔG / RT)

K = exp ( - 1.8 x 10⁴ J /( 8.314 J/K x 873 K)) = 8.2 x 10⁻²

8 0

3 years ago

Determine the mass in grams of 3.75 x 10^21 atoms of zinc. (the mass of one mole of zinc is 65.39 g)

Nastasia [14]

Answer: The mass in $3.75 \times 10^{21}$ atoms of zinc is 0.405 g.

Explanation:

Given: Atoms of zinc = $3.75 \times 10^{21}$

It is known that 1 mole of every substance contains $6.022 \times 10^{23}$ atoms. So, the number of moles in given number of atoms is as follows.

$Moles = \frac{3.75 \times 10^{21}}{6.022 \times 10^{23}}\\= 0.622 \times 10^{-2}\\= 0.0062 mol$

As moles is the mass of a substance divided by its molar mass. So, mass of zinc (molar mass = 65.39 g/mol) is calculated as follows.

$Moles = \frac{mass}{molar mass}\\0.0062 mol = \frac{mass}{65.39 g}\\mass = 0.405 g$

Thus, we can conclude that the mass in $3.75 \times 10^{21}$ atoms of zinc is 0.405 g.

6 0

3 years ago

Calculate the number of moles contained in 550ml of carbon dionide at stp

g100num [7]

The answer is 20 I think

3 0

3 years ago

The formation of ammonia is represented by the equation N2(g) + 3H2(g) ⇌ 2NH3(g). Determine the enthalpy of formation of ammonia

Savatey [412]

Answer:

$\Delta _fH_{NH_3}=-66\frac{kJ}{mol}$

Explanation:

Hello!

In this case, since the study of the bond energy allows us to compute the enthalpies of some reactions, for this combination reaction by which ammonia is yielded, we understand the enthalpy of reaction equals the enthalpy of formation of ammonia, and, in terms of the bonds energy we can write:

$\Delta _fH_{NH_3}=Delta _rH=\Sigma \Delta H(bonds \ broken)-\Sigma \Delta H(bonds \ formed)$

Whereas the bonds enthalpy of those bonds that get broken cover the N≡N and the three H-H bonds at the reactants side and the enthalpy of those bonds that are formed cover the six N-H bonds at the products; which means we obtain:

$\Delta _fH_{NH_3}=942\frac{kJ}{mol} +3*436\frac{kJ}{mol}-6*386\frac{kJ}{mol}\\\\\Delta _fH_{NH_3}=-66\frac{kJ}{mol}$

Which differs from the theoretical value that is -46 kJ/mol.

Best regards!

7 0

3 years ago