"A red giant is a star that has exhausted the primary supply of hydrogen fuel at its core. An average-sized star like our Sun will spend the final 10 percent of its life as a red giant. In this phase, a star's surface temperature drops to between 3,140 and 6,741°F (1,727 and 3,727°C) and its diameter expands to 10 to 1,000 times that of the Sun. The star takes on a reddish color, which is what gives it its name."
Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
<em />
Answer:
11.4
Explanation:
Step 1: Given data
- Concentration of the base (Cb): 0.300 M
- Basic dissociation constant (Kb): 1.8 × 10⁻⁵
Step 2: Write the dissociation equation
NH₃(aq) + H₂O(l) ⇄ NH₄⁺(aq) + OH⁻(aq)
Step 3: Calculate the concentration of OH⁻
We will use the following expression.
![[OH^{-} ]=\sqrt{Kb \times Cb } = \sqrt{1.8 \times 10^{-5} \times 0.300 } = 2.3 \times 10^{-3} M](https://tex.z-dn.net/?f=%5BOH%5E%7B-%7D%20%5D%3D%5Csqrt%7BKb%20%5Ctimes%20Cb%20%7D%20%3D%20%5Csqrt%7B1.8%20%20%5Ctimes%2010%5E%7B-5%7D%20%5Ctimes%200.300%20%7D%20%3D%202.3%20%5Ctimes%2010%5E%7B-3%7D%20M)
Step 4: Calculate the pOH
We will use the following expression.
![pOH =-log[OH^{-} ]= -log(2.3 \times 10^{-3} M) = 2.6](https://tex.z-dn.net/?f=pOH%20%3D-log%5BOH%5E%7B-%7D%20%5D%3D%20-log%282.3%20%5Ctimes%2010%5E%7B-3%7D%20M%29%20%3D%202.6)
Step 5: Calculate the pH
We will use the following expression.
