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mamaluj [8]
3 years ago
13

A 0.6-m3 rigid tank is filled with saturated liquid water at 135°C. A valve at the bottom of the tank is now opened, and one-hal

f of the total mass is withdrawn from the tank in liquid form. Heat is transferred to water from a source of 210°C so that the temperature in the tank remains constant. Assume the surroundings to be at 25°C and 100 kPa.
Chemistry
1 answer:
Lemur [1.5K]3 years ago
6 0

The given question is incomplete. The complete question is as follows.

A 0.6-m3 rigid tank is filled with saturated liquid water at 135°C. A valve at the bottom of the tank is now opened, and one-half of the total mass is withdrawn from the tank in liquid form. Heat is transferred to water from a source of 210°C so that the temperature in the tank remains constant. Assume the surroundings to be at 25°C and 100 kPa. Determine the amount of heat transfer.

Explanation:

First, we will determine the initial mass from given volume and specific volume as follows.

              m_{1} = \frac{V}{\alpha_{1}}

                         = \frac{0.6}{0.001075}kg

                         = 558.14 kg

Hence, the final mass and mass that has left the tank are as follows.

             m_{2} = m_{out} = \frac{1}{2}m_{1}  

                          = \frac{1}{2} \times 558.14 kg

                          = 279.07 kg

Now, the final specific volume is as follows.

          \alpha_{2} = \frac{V}{m_{2}}

                        = \frac{0.6}{279.07} m^{3}/kg

                        = 0.00215 m^{3}/kg

Final quality of the mixture is determined actually from the total final specific volume and the specific volumes of the constituents for the given temperature are as follows.

           q_{2} = \frac{\alpha_{2} - \alpha_{liq135}}{(\alpha_{vap} - \alpha_{liq})_{135}}

                        = \frac{0.00215 - 0.001075}{0.58179 - 0.001075}

                        = 1.85 \times 10^{-3}

Hence, the final internal energy will be calculated as follows.

          u_{2} = u_{liq135} + q_{2}u_{vap135}

                      = (567.41 + 1.85 \times 10^{-3} \times 1977.3) kJ/kg

                      = 571.06 kJ/kg

Now, we will calculate the heat transfer as follows.

            \Delta U = Q - m_{out}h_{out}

      m_{2}u_{2} - m_{1}u_{1} = Q - m_{out}h_{out}

                Q = (279.07 \times 571.06 - 558.14 \times 567.41 + 279.07 \times 567.75) kJ

                    = 1113.5 kJ

Thus, we can conclude that amount of heat transfer is 1113.5 kJ.

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<u>Answer:</u> The volume of acid and water that must be mixed will be 4.8 L and 11.2 L

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