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mamaluj [8]
3 years ago
13

A 0.6-m3 rigid tank is filled with saturated liquid water at 135°C. A valve at the bottom of the tank is now opened, and one-hal

f of the total mass is withdrawn from the tank in liquid form. Heat is transferred to water from a source of 210°C so that the temperature in the tank remains constant. Assume the surroundings to be at 25°C and 100 kPa.
Chemistry
1 answer:
Lemur [1.5K]3 years ago
6 0

The given question is incomplete. The complete question is as follows.

A 0.6-m3 rigid tank is filled with saturated liquid water at 135°C. A valve at the bottom of the tank is now opened, and one-half of the total mass is withdrawn from the tank in liquid form. Heat is transferred to water from a source of 210°C so that the temperature in the tank remains constant. Assume the surroundings to be at 25°C and 100 kPa. Determine the amount of heat transfer.

Explanation:

First, we will determine the initial mass from given volume and specific volume as follows.

              m_{1} = \frac{V}{\alpha_{1}}

                         = \frac{0.6}{0.001075}kg

                         = 558.14 kg

Hence, the final mass and mass that has left the tank are as follows.

             m_{2} = m_{out} = \frac{1}{2}m_{1}  

                          = \frac{1}{2} \times 558.14 kg

                          = 279.07 kg

Now, the final specific volume is as follows.

          \alpha_{2} = \frac{V}{m_{2}}

                        = \frac{0.6}{279.07} m^{3}/kg

                        = 0.00215 m^{3}/kg

Final quality of the mixture is determined actually from the total final specific volume and the specific volumes of the constituents for the given temperature are as follows.

           q_{2} = \frac{\alpha_{2} - \alpha_{liq135}}{(\alpha_{vap} - \alpha_{liq})_{135}}

                        = \frac{0.00215 - 0.001075}{0.58179 - 0.001075}

                        = 1.85 \times 10^{-3}

Hence, the final internal energy will be calculated as follows.

          u_{2} = u_{liq135} + q_{2}u_{vap135}

                      = (567.41 + 1.85 \times 10^{-3} \times 1977.3) kJ/kg

                      = 571.06 kJ/kg

Now, we will calculate the heat transfer as follows.

            \Delta U = Q - m_{out}h_{out}

      m_{2}u_{2} - m_{1}u_{1} = Q - m_{out}h_{out}

                Q = (279.07 \times 571.06 - 558.14 \times 567.41 + 279.07 \times 567.75) kJ

                    = 1113.5 kJ

Thus, we can conclude that amount of heat transfer is 1113.5 kJ.

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Considering the Hess's Law, the enthalpy change for the reaction is -906.4 kJ/mol.

<h3>Hess's Law</h3>

Hess's Law indicates that the enthalpy change in a chemical reaction will be the same whether it occurs in a single stage or in several stages. That is, the sum of the ∆H of each stage of the reaction will give us a value equal to the ∆H of the reaction when it occurs in a single stage.

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Because of the way formation reactions are defined, any chemical reaction can be written as a combination of formation reactions, some going forward and some going back.

In this case, first, to obtain the enthalpy of the desired chemical reaction you need 4 moles of NH₃ on reactant side and it is present in first equation on product side. So you need to invert the reaction, and when an equation is inverted, the sign of delta H also changes.

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In summary, you know that three equations with their corresponding enthalpies are:

Equation 1: 2 4 NH₃ → N₂ + 6 H₂  ΔH = 183.6 kJ/mol

Equation 2:  2 N₂ + 2 O₂ → 4 NO     ΔH = 361.1 kJ/mol

Equation 3: 6 H₂ + 3 O₂→ 6 H₂O     ΔH = -1,451.1 kJ/mol

Adding or canceling the reactants and products as appropriate, and adding the enthalpies algebraically, you obtain:

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