Explanation:
The observable visible spectrum of Cr(acac)3 complex is different from that of
[Cr(en)3]Br3 due to strength of bonded ligand in the coordination sphere.
en is a strong field ligand compared to acac thus pairing occurs. In both the complexes
Cr is in +3 state, configuration [Ar] 3d^3. There are 3 unpaired e in Cr(acac)3 whereas 1 unpaired e in [Cr(en)3]Br3 due to pairing.
Answer:
hydrogen peroxide is a compound
The mass of electrons , i just did the same test and got it right
Answer:
27 min
Explanation:
The kinetics of an enzyme-catalyzed reaction can be determined by the equation of Michaelis-Menten:
![v = \frac{vmax[S]}{Km + [S]}](https://tex.z-dn.net/?f=v%20%3D%20%5Cfrac%7Bvmax%5BS%5D%7D%7BKm%20%2B%20%5BS%5D%7D)
Where v is the velocity in the equilibrium, vmax is the maximum velocity of the reaction (which is directed proportionally of the amount of the enzyme), Km is the equilibrium constant and [S] is the concentration of the substrate.
So, initially, the velocity of the formation of the substrate is 12μmol/9min = 1.33 μmol/min
If Km is a thousand times smaller then [S], then
v = vmax[S]/[S]
v = vmax
vmax = 1.33 μmol/min
For the new experiment, with one-third of the enzyme, the maximum velocity must be one third too, so:
vmax = 1.33/3 = 0.443 μmol/min
Km will still be much smaller then [S], so
v = vmax
v = 0.443 μmol/min
For 12 μmol formed:
0.443 = 12/t
t = 12/0.443
t = 27 min
[Co(CN)₆]³⁻ → Yellow
[Co(NH₃)₆]³⁺ → Orange
[CoF₆]³⁻ → Blue
Explanation:
- All the given compounds have octahedral geometry but the ligand in each are different with the same metal ion.
- Ligands strength order: CN⁻ > NH₃ > F⁻
- The ligand CN will act as a strong field ligand so that the splitting is maximum when compared to NH₃ and F⁻
- If the splitting is more, the energy required for transition is more, and the wavelength is inversely proportional to energy.
- So CN complex will absorb at lower wavelength (yellow color)
