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Serggg [28]
3 years ago
5

According to the ideal gas law, a 9.585 mol sample of krypton gas in a 0.8032 L container at 504.9 K should exert a pressure of

494.4 atm. What is the percent difference between the pressure calculated using the van der Waals' equation and the ideal pressure? For Kr gas, a = 2.318 L2atm/mol2 and b = 3.978×10-2 L/mol. %
Chemistry
1 answer:
natka813 [3]3 years ago
6 0

Answer:

1.17%

Explanation:

The pressure using vander waals' equation = 610.955atm

The difference

  • 610.955-494.4 =116.555atm

The % difference = 1.17%

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CARBON! :) it’s the 6th element
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3 years ago
. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are
olga nikolaevna [1]

<u>Answer:</u> The standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

K_{sp}\text{ of }Ag_2S=8\times 10^{-51}

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K

where,

\Delta G^o = standard Gibbs free energy = ?

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K = equilibrium constant or solubility product = 8\times 10^{-51}

Putting values in above equation, we get:

\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ

For the given chemical equation:

Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)

The equation used to calculate Gibbs free change is of a reaction is:  

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]

The equation for the Gibbs free energy change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]

We are given:

\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ

Putting values in above equation, we get:

285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol

Hence, the standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

8 0
3 years ago
A mixture of gaseous reactants is put into a cylinder, where a chemical reaction tums them into gaseous products. The cylinder h
erastova [34]

Answer:

The reaction is exothermic

The temperature of the water bath goes up

Explanation:

An exothermic reaction is one in which energy flows out of the reaction system.

In this case, the system is the reaction vessel while the surrounding is the water bath. We see in the question that 300.1J of heat flows out of the system during the reaction. This is heat lost to the surroundings showing that the reaction is exothermic.

As energy is lost to the surroundings, the temperature of the water bath rises accordingly.

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Which pair below describes isotopes of the same element? A) an atom with 6 protons and 8 neutrons - an atom with 8 protons and 6
V125BC [204]

<u>Answer:</u> The atom with 6 protons and 6 neutrons and an atom with 6 protons and 7 neutrons are the isotopes of same element.

<u>Explanation:</u>

Isotopes are defined as the chemical species that belong to the same element but differ in their mass number.

This also means that the chemical species have same number of protons and electrons but different number of neutrons.

Atomic number is defined as the number of protons or electrons that are present in a neutral atom.

Atomic number = number of protons = number of electrons

Mass number is defined as the sum of number of protons and neutrons that are present in an atom.

Mass number = Number of protons + Number of neutrons

From the given options:

The elements having same number of protons will be the isotopes of same element.

Hence, the atom with 6 protons and 6 neutrons and an atom with 6 protons and 7 neutrons are the isotopes of same element.

8 0
3 years ago
4. Magnesium and oxygen undergo a chemical reaction to
erastovalidia [21]

Answer:

About 16.1 grams of oxygen gas.

Explanation:

The reaction between magnesium and oxygen can be described by the equation:
\displaystyle 2\text{Mg} + \text{O$_2$} \longrightarrow 2\text{MgO}

24.4 grams of Mg reacted with O₂ to produce 40.5 grams of MgO. We want to determine the mass of O₂ in the chemical change.

Compute using stoichiometry. From the equation, we know that two moles of MgO is produced from every one mole of O₂. Therefore, we can:

  1. Convert grams of MgO to moles of MgO.
  2. Moles of MgO to moles of O₂
  3. And moles of O₂ to grams of O₂.

The molecular weights of MgO and O₂ are 40.31 g/mol and 32.00 g/mol, respectively.

Dimensional analysis:

\displaystyle 40.5\text{ g MgO} \cdot \frac{1\text{ mol MgO}}{40.31\text{ g MgO}} \cdot \frac{1\text{ mol O$_2$}}{2\text{ mol MgO}} \cdot \frac{32.00\text{ g O$_2$}}{1\text{ mol O$_2$}} = 16.1\text{ g O$_2$}

In conclusion, about 16.1 grams of oxygen gas was reacted.

You will obtain the same result if you compute with the 24.4 grams of Mg instead:

\displaystyle 24.4\text{ g Mg}\cdot \frac{1\text{ mol Mg}}{24.31\text{ g Mg}} \cdot \frac{1\text{ mol O$_2$}}{1\text{ mol Mg}} \cdot \frac{32.00\text{ g O$_2$}}{1\text{ mol O$_2$}} = 16.1\text{ g O$_2$}

3 0
2 years ago
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